采用固相反应法制备了(1-c)CaWO4-xLizWO。(O≤x≤0.14)微波陶瓷,研究了Li2WO4作为第二相对CaWO。微波陶瓷的低温烧结特性和微波性能的影响。结果表明,Li2WO4相的存在能明显降低CaWO。的烧结温度,并且随着z的增加,(1-x)CaWO4-xLi2WO4(O≤z≤0.14)陶瓷体系的最佳烧结温度降低。当x=0.1,在900℃下烧结2h,该陶瓷材料的介电常数ε1=9.002,品质因数与频率之积Q×f=11.76×10^4GHz,谐振频率温度系数r1=55×10^-6/℃。在此基础上采用w(CaTiO3)=5.0%调节其谐振频率温度系数到0,调节后的微波介电性能为ε1=10.312,Q×f=5.36×10。GHz,rr约为0
The (1-x) CaWO4-xLi2 WO4 (0≤x≤0.14) microwave ceramics were prepared by the solid state re- action method. The effect of Li2WO4 as second phase on the low-temperature sintering and microwave dielectric properties of CaWO4 was investigated. The results showed that the existing LizWO4 phase can reduce the sintering temperature of CaWO4 significantly; furthermore, with x increase, the optimal sintering temperature of (1-x) Ca- WO4-xLizW04 (O≤x≤O. 14) ceramic system decreased. At x:0. 1, the (1-x) CaWO4-xLizW04 ceramics sin- tered at 900 ℃ for 2 h presented excellent microwave dielectric properties. The dielectric constant of cr is 9. 002, the Q X f is 11.76 X 104 GHz and the temperature coefficient of resonant frequency of rl is --55 × 10^6/℃. On this ba- s is,w (CaTiO3) = 5.0 % was used to adjust the temperature coefficient of resonant frequency to zero. The micro- wave dielectric properties after adjusting was εr = 10. 312 ,QX f = 5.36 × 104 GHz and rsvp.0.