中文摘要：

采用高温固相烧结法制备了Ho^（3＋）单掺杂、Ho^（3＋）/Yb^（3＋）共掺杂、Ho^（3＋）/Er^（3＋）共掺杂和Ho^（3＋）/Yb^（3＋）/Er^（3＋）共掺杂等系列硼硅酸盐玻璃,测量了样品的激发光谱和发射光谱。结果表明：Ho^（3＋）单掺杂样品的激发光谱与发射光谱的强度随其浓度增加而逐渐减弱,原因是高浓度掺杂导致Ho^（3＋）离子产生猝灭效应;Ho^（3＋）/Yb^（3＋）共掺杂玻璃由于Yb^（3＋）离子的敏化作用,光谱强度增强;Ho^（3＋）/Yb^（3＋）/Er^（3＋）共掺杂样品中Ho^（3＋）离子向Er^（3＋）离子发生能量传递,Ho^（3＋）离子的激发光谱和发射光谱强度均减弱。同时讨论了峰值波长为550nm宽带发射峰的发光机制。

英文摘要：

A series of holmium ions doped borosilicate glass,including Ho（3＋）-doped,Ho（3＋）/Er（3＋）-doped,Ho（3＋）/ Yb（3＋）-doped and Ho（3＋）/Yb（3＋）/Er（3＋）-doped galss,have been prepared by high-temperature melting.The up-conversion excitation spectra and emission spectra of the samples decrease.The analysis result reveals that both the intensities of excitation spectra and emission spectra were weaken with the Ho（3＋）concentration.The spectral intensities of Ho（3＋）/Yb（3＋）-doped borosilicate glass increase with the increase of Ho（3＋）concentration because of the sensitization of Yb（3＋）.The excitation and emission spectra intensities of Ho~（3＋）/Yb~（3＋）/Er~（3＋）-doped borosilicate glass are weak,and the reason is the energy transfers from Ho~（3＋）ions to Er~（3＋）ions through energy resonant transfer process.Meanwhile the luminescence mechanism of broadband emission peaked at 550 nm is analyzed.