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Stable isotope fractionation of chlorine during evaporation of brine from a saline lake
  • ISSN号:1001-6538
  • 期刊名称:Chinese Science Bulletin
  • 时间:0
  • 页码:1833-1843
  • 分类:P597[天文地球—地球化学;天文地球—地质学] TS39[轻工技术与工程]
  • 作者机构:[1]CAS Key Laboratory of Salt Lake Resources and Chemistry, Qinghai Institute of Salt Lakes, Chinese Academy of Sciences, Xining 810008, China, [2]State Key Laboratory of Loess and Quaternary Geology, Institute of Earth Environment, Chinese Academy of Sciences, Xi'an 710075, China, [3]Graduate University, Chinese Academy of Sciences, Beijing 100049, China
  • 相关基金:The authors sincerely thank Prof Liu Weiguo for his hells with the comple tion of this research. This work was supported by the National Basic Re search Program of China (2011 CB403000) and the National Natural Science Foundation of China (40776071, 40976074 and 41173019).
  • 相关项目:珊瑚硼氧同位素和化学组成作为海洋环境代用指标可行性研究-珊瑚养殖实验
中文摘要:

从盐的卡汉·莱克的盐水在 28 点被蒸发吗?

英文摘要:

Brine from the saline Qarhan Lake was evaporated at 28±2 ℃in a clean environment. Two groups of experiments were conducted; one with complete separation of precipitate and brine at different stages of evaporation, and the other with continuous precipita- tion during the evaporation. Seventy-nine precipitate and brine samples were collected during the experiments, and the δ^37Cl values were determined using an improved thermal ionization mass spectrometry procedure for precise measurement of chlorine isotopes based on Cs2Cl^+ ions. Based on the concentrations of Na^+, K^+, and Mg^2+, evaporation was divided into three main precipitation stages as follows: halite dominant, carnallite dominant, and bischofite dominant. The δ^37Clsolid and δ^37Clliquid values of the precipitate and coexisting brine samples at different stages showed the following characteristics. The precipitates were enriched with δ^37Cl relative to the coexisting brine samples, and the δ^37Cl of both the precipitate and brine samples decreased gradually during evaporation. The fractionation factors (ah) between halite and brine were the highest, followed by that (ac) between carnallite and brine, and then that (ab) between bischofite and brine. The ac and ab values of less than one, which indicate the precipitate is enriched in 35^Cl, were found when the evaporation process entered a new stage. However, the δ^37Cl values of carnallite, bischofite, and the coexisting brine samples decreased during evaporation. The residual brine is a 35^Cl reservoir. The experimental phenomena were consistent with the δ^37Cl values in saline deposits in the literature. δ^37Cl can be used as an indicator of brine evaporation processes, which is important in the exploration of sylvinite deposits.

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