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Facile Synthesis of Phosphorus N-Fluoroalkanesulfonyl Amidines by Cu-catalyzed One-pot Three-component Reaction
  • ISSN号：1001-604X
  • 期刊名称：《中国化学：英文版》
  • 分类：O626[理学—有机化学;理学—化学] TQ242.1[化学工程—有机化工]
  • 作者机构：[1]Key Laboratory of Synthetic Chemistry of Natural Substances and Key Laboratory of Organofiuorine Chemistry, Shanghai Institute of Organic Chemistry, 345 Lingling Road, Shanghai 200032, China
  • 相关基金：Project supported by the National Natural Science Foundation of China （Nos. 21032006, 20172064）, and the QT Program, Shanghai Natural Science Council.
作者： 张振华[1], 熊婉婷[1], 顾继伟[1], 朱士正[1]
关键词： 杂环化合物, 氟化, 双击, MOD, BF4, 内酯, Selectfluor, electrophilic fluorination, 4,5-allenoic acid, 4,5-allenoic tosylamide, allyl difluoride
中文摘要：

1,1-difluoroallyl 的新奇、灵巧的准备通过 4,5-allenoic 酸的直接双的 electrophilic 氟化作用在中等收益代替了五成员的内酯或 pyrrolidines 或有 SelectfluorTM F-TEAD-BF4 的 tosylamides 被描述。

英文摘要：

A novel and facile preparation of l,l-difluoroallyl substituted five-membered lactones or pyrrolidines in mod- erate yields through direct double electrophilic fluorination of 4,5-allenoic acids or tosylamides with SelectfluorTM F-TEAD-BF4 is described.

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期刊信息
  • 《中国化学：英文版》
  • 主管单位:
  • 主办单位:中国化学会
  • 主编：
  • 地址：上海市枫林路354号中科院上海有机化学研究所
  • 邮编：200032
  • 邮箱：
  • 电话：021-54925243
  • 国际标准刊号：ISSN：1001-604X
  • 国内统一刊号：ISSN：31-1547/O6
  • 邮发代号:4-646
  • 获奖情况:
  • 中国期刊方阵“双高”期刊
  • 国内外数据库收录:
  • 美国化学文摘（网络版）,荷兰文摘与引文数据库,美国科学引文索引（扩展库）,日本日本科学技术振兴机构数据库,英国英国皇家化学学会文摘
  • 被引量:175