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Palladium-Catalyzed Cross-Coupling of Fluorinated Vinyl Chlorides with Terminal Alkynes： A General Protocol to Fluorinated Enynes
  • ISSN号：1001-604X
  • 期刊名称：《中国化学：英文版》
  • 时间：0
  • 分类：O623.124[理学—有机化学;理学—化学] TQ153.15[化学工程—电化学工业]
  • 作者机构：[1]Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China
  • 相关基金：Acknowledgement The authors gratefully acknowledge the financial support from National Basic Research Program of China （Nos. 2012CB821600, 2010CB126103）, the Key Program of Natural Science Foundation of China （No.21032006）, National Natural Science Foundation of China （Nos. 21172245, 21172244, B020304）, Agroscientific Research in the Public Interest （No. 201103007）, the National Key Technologies R＆D Program （No. 2011BAE06B05）, Shanghai Scientific Research Program （No. 10XD1405200）, and SIOC.
作者： Sheng Chen Chunfa Xu Long Lu Qilong Shen[1]
关键词： 氯化物, 乙烯基, 末端炔烃, 交叉偶联, 烯炔, 议定书, 钯催化, 氟化, fluorine, enyne, palladium, chlorotrifluoroethylene
中文摘要：

为氟化的结合的 enynes 的准备的一个有效、划算的方法被描述。方法与象氯化物，胺， cyano 和酉旨组那样的许多功能的组兼容。方法能也被扩大到联合(R， Z ) 有中等收益的 -3-(2-chloro-1,2-difluorovinyl)-4-alkyloxazolidin-2-one (3 ) 。

英文摘要：

An efficient and cost-effective method for the preparation of fluorinated conjugated enynes was described, tile method was compatible with a variety of functional groups such as chloride, amine, cyano and ester group. The method could also be extended to the coupling of （R,Z）-3-（2-chloro-1,2-difluorovinyl）-4-alkyloxazolidin-2-one （3） with moderate yields.

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期刊信息
  • 《中国化学：英文版》
  • 主管单位:
  • 主办单位:中国化学会
  • 主编：
  • 地址：上海市枫林路354号中科院上海有机化学研究所
  • 邮编：200032
  • 邮箱：
  • 电话：021-54925243
  • 国际标准刊号：ISSN：1001-604X
  • 国内统一刊号：ISSN：31-1547/O6
  • 邮发代号:4-646
  • 获奖情况:
  • 中国期刊方阵“双高”期刊
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  • 被引量:175