以取代芳醚为原料,碘苯醋酸酯为氧化剂,二氯甲烷为溶剂,在醋酸铑催化下合成了一系列醌类化合物,其结构经1HNMR,13CNMR和HR-MS确证。
A series of quinone compounds were synthesized by catalyzed oxidation from substituted aromatic ethers using diacetoxyiodobenzene as the oxidant, rhodium acetate as the catalyst and methylene chloride as the solvent. The structures were confirmed by 1H NMR, 13C NMR and MS.