位置：成果数据库 > 期刊 > 期刊详情页
NASICON型电解质材料Li1+xErxZr2-x（PO4）3（0.1≤x≤0.2）的制备与性能
  • ISSN号：1002-185X
  • 期刊名称：《稀有金属材料与工程》
  • 时间：0
  • 分类：TQ174[化学工程—陶瓷工业;化学工程—硅酸盐工业]
  • 作者机构：景德镇陶瓷学院, 清华大学新型陶瓷与精细工艺国家重点实验室
  • 相关基金：创新研究群体科学基金项目(51221291)
作者： 刘美景, 魏红康, 汪长安
关键词： 锂电池, 固态电解质, NASICON
中文摘要：

以Li2CO3、ZrO2、Er2O3、（NH4）2HPO4为初始原料,采用传统的固相法合成了Li Zr2（PO4）3基NASICON型固态电解质材料Li1+xErxZr2-x（PO4）3（x=00.2）。通过无压烧结和放电等离子烧结法（SPS）烧结得到致密的电解质片,采用无压烧结过程中在样品中加入少许的PVA使得样品烧结致密。利用XRD、SEM、EIS分别测得样品的结构、形貌以及电性能。结果表明:通过SPS烧结的样品致密度可以达到92.6%。使用SPS烧结后的样品Li1.15Er0.15Zr1.85（PO4）3在常温下的晶粒和总电导率分别为2.2×10-4和8.8×10-6 S·cm-1。样品的激活能为0.36 e V。

同期刊论文项目
信息功能陶瓷材料科学
期刊论文 338
同项目期刊论文
Ferromagnetic and optical behaviors observed in Mn-doped ZnO-based thin films
Magnetic coupling effect of Mie resonance-based metamaterial with inclusion of split ring resonators
Large enhancement of the recoverable energy storage density and piezoelectric response in relaxor-fe
Effects of Li source on microstructure and ionic conductivity of Al-contained Li6.75La3Zr1.75Ta0.25O
Purely Electric-Field-Driven Perpendicular Magnetization Reversal
Investigation on the synthesis procedure of ultrafine monodispersed BaTiO3 powders by solvothermal m
Effects of seed layer and crystallization process on crystal orientation and properties of NKBT thin
Magnetically tunable microwave bandpass filter structure composed of ferrite rods and metallic slits
Direct observation of lithium dendrites inside garnet-type lithium-ion solid electrolyte
Enhanced thermoelectric performance of La-doped BiCuSeO by tuning band structure
Synthesis, characterization and dielectric properties of surface functionalized ferroelectric cerami
Complex Effect of Sm3+/W6+ Codoping on alpha-beta Phase Transformation and Phonon Scattering of Oxyg
Sintering behavior and reliability characteristics of BaTiO3-based ceramics prepared by different me
Structure, Microwave Dielectric Properties and Thermally Stimulated Depolarization Currents of (1-x)
Great reduction of loss at high electric field in the polyvinylidene fluoride/aromatic polythiourea
Dual-band-enhanced Transmission through a Subwavelength Aperture by Coupled Metamaterial Resonators
Electronic structure, optical and dielectric properties of BaTiO3/CaTiO3/SrTiO3 ferroelectric superl
A comprehensive review on synthesis methods for transition-metal oxide nanostructures
Preparation and characterization of highly crystallized BaTiO3 layer on Ni nanoparticles
Terahertz time domain spectroscopic investigation of spin reorientation transitions in HoFeO3
Composite Based on Fe3O4@BaTiO3 Particles and Polyvinylidene Fluoride with Excellent Dielectric Prop
Synthesis and magnetoelectric effect of composites with CoFe2O4-epoxy embedded in 3-1 type porous PZ
Effects of thermal anneal temperature on electrical properties and energy-storage density of Bi(Ni1/
A novel linear piezoelectric actuator with two working principles of standing and traveling wave vib
Evaluating the electro-optical effect in alternating current-voltage-modulated Kerr response for mul
Grain Size Effects on Piezoelectric Properties and Domain Structure of BaTiO3 Ceramics Prepared by T
Raman Spectra and Phase Transition in (1-x) BiScO3-xPbTiO(3) Nanopowders
Voltage-controlled Kerr response in Ni/Pb(Zr0.52Ti0.48)O-3 heterostructures
Film size-dependent voltage-modulated magnetism in multiferroic heterostructures
A study on (K, Na) NbO3 based multilayer piezoelectric ceramics micro speaker
Voltage-driven perpendicular magnetic domain switching in multiferroic nanoislands
High piezoelectricity due to multiphase coexistence in low-temperature sintered (Ba,Ca)(Ti,Sn)O-3-Cu
Comprehensive investigation of elastic and electrical properties of Li/Ta-modified (K,Na)NbO3 lead-f
Synthesis and characterization of CaTiO3-(Sm,Nd)AlO3 microwave ceramics via sol-gel method
High piezoelectricity of BaTiO3-CaTiO3-BaSnO3 lead-free ceramics
A screw-thread-type ultrasonic actuator based on a Langevin piezoelectric vibrator
Non-Volatile 180 degrees Magnetization Reversal by an Electric Field in Multiferroic Heterostructure
Temperature dependence of magnetoelectric coupling in FeBSiC/PZT/FeBSiC laminates
Dual band microwave ferromagnetic resonance absorption in annealed cobalt nanowire arrays
Garnet-type Li6.4La3Zr1.4Ta0.6O12 thin sheet: Fabrication and application in lithium-hydrogen peroxi
Theoretical Prediction and Experimental Validation of Enhancing the Piezoelectric Properties of (K,
Multi-Enhanced-Phonon Scattering Modes in Ln-Me-A Sites co-substituted LnMeA(11)O(19) Ceramics
Excess lithium salt functions more than compensating for lithium loss when synthesizing Li6.5La3Ta0.
Enhancement of thermoelectric performance in Cd-doped Ca3Co4O9 via spin entropy, defect chemistry an
Effect of Rare Earth Oxide Content on Nanograined Base Metal Electrode Multilayer Ceramic Capacitor
Thickness dependence of magnetoelectric response for composites of Pb(Zr0.52Ti0.48)O-3 films on CoFe
High-frequency ferromagnetic resonance of Co nanowire arrays
Grain size effect on electrical and reliability characteristics of modified fine-grained BaTiO3 cera
Displacement of Ta-O bonds near polymorphic phase transition in Li-, Ta-, and Sb-modified (K, Na) Nb
Enhanced bipolar fatigue resistance in CaZrO3-modified (K,Na) NbO3 lead-free piezoceramics
Hydrothermal synthesis and effects of pH values on properties of CdWO4 powders
On the elastically coupled magnetic and ferroelectric domains: A phase-field model
Piezoelectric Properties of a Pioneering 3-1 Type PZT/Epoxy Composites Based on Freeze-Casting Proce
Grain size effect on piezoelectric and ferroelectric properties of BaTiO3 ceramics
Enhancing piezoelectric coefficient d(33) in LiF-doped BaTiO3 ceramics by optimizing excess Ba conte
Obtaining ultimate functionalities in nanocomposites: Design, control, and fabrication
Shifted Morphotropic Phase Boundary in [111]-Oriented Nb-Doped Pb(ZrxTi1-x)O-3 Epitaxial Films: Insi
Improved Energy Storage Properties of Fine-Crystalline BaTiO3 Ceramics by Coating Powders with Al2O3
Magnetically tunable broadband transmission through a single small aperture
Tunable metamaterial bandstop filter based on ferromagnetic resonance
Anisotropic ferromagnetic behaviors in highly orientated epitaxial NiO-based thin films
Magnetization Reversal by Out-of-plane Voltage in BiFeO3-based Multiferroic Heterostructures
Tunable Dielectric Properties of Ferrite-Dielectric Based Metamaterial
Core-shell grain structures and dielectric properties of Na0.5K0.5NbO3-LiTaO3-BiScO3 piezoelectric c
Magnetically tunable dual-band transmission through a single subwavelength aperture
Microwave Dielectric Properties and Thermally Stimulated Depolarization Currents of (1-x)MgTiO3-xCa(
Magnetic and electrical properties of Z-type hexaferrites sintered in different atmospheres
Magnetically tunable wideband microwave filter using ferrite-based metamaterials
Electric-field-driven magnetization reversal in square-shaped nanomagnet-based multiferroic heterost
Nanodomains in KNN- Based Lead- Free Piezoelectric ceramics: Origin of Strong Piezoelectric Properti
The phase structure and electric properties of low-temperature sintered (K, Na)NbO3-based piezoceram
Structure and composition characterization of Lead-free (K, Na)NbO3 piezoelectric nanorods synthesiz
Study of polymorphic phase boundary in (Na,K,Li) (Nb,Ta,Sb)O-3 piezoelectric ceramics
Quasi-epitaxial barium hexaferrite thin films prepared by a topotactic reactive diffusion process
Orientation-dependent piezoelectricity and domain characteristics of tetragonal Pb(Zr-0.3,Ti-0.7)(0.
Highly dispersed SrTiO3 nanocubes from a rapid sol-precipitation method
Magnetic-Field-Orientation Dependent Magnetoelectric Effect in FeBSiC/PZT/FeBSiC Composites
X-ray absorption near-edge spectroscopy study on Ge-doped Li7La3Zr2O12: enhanced ionic conductivity
Phase structures and microwave dielectric properties of xCaTiO(3)-(1-x)Sm0.9Nd0.1AlO3 ceramics
Engineering domain structures in nanoscale magnetic thin films via strain
High Li+ conduction in NASICON-type Li1+x,YxZr2-x(PO4)(3) at room temperature
Ferrite based metamaterials with thermo-tunable negative refractive index
Phase transition and high piezoelectricity in (Ba,Ca)(Ti1-xSnx)O-3 lead-free ceramics
High-Energy-Storage Density Capacitors of Bi(Ni1/2Ti1/2)O-3-PbTiO3 Thin Films with Good Temperature
Reconfigurable Sensing Antenna With Novel HDPE-BST Material for Temperature Monitoring
Multi-band negative refractive index in ferrite-based metamaterials
High-temperature thermoelectric properties of La and Fe co-doped Ca-Co-O misfit-layered cobaltites c
Interfacial Diffusion Behavior in Ni-BaTiO3 MLCCs with Ultra-Thin Active Layers
Magnetic properties of in-plane oriented barium hexaferrite thin films prepared by direct current ma
Full 180 degrees Magnetization Reversal with Electric Fields
Strain-induced modulation of magnetic anisotropy in Co/BaTiO3 composite
Piezoelectricity of lead-free (K, Na)NbO3 nanoscale single crystals
Magnetically tunable Mie resonance-based dielectric metamaterials
Photocatalytic and magnetic behaviors of BiFeO3 thin films deposited on different substrates
Total broadband transmission of microwaves through a subwavelength aperture by localized E-field cou
Rapid Formation of Nanocrystalline BaTiO3 and Its Highly Stable Sol
Microwave Dielectric Properties and Thermally Stimulated Depolarization Currents of MgF2-Doped Diops
Effect of calcining and Al doping on structure and conductivity of Li7La3Zr2O12
Investigation on co-fired multilayer KNN-based lead-free piezoceramics
Microwave Dielectric Properties and Thermally Stimulated Depolarization Currents Study of (1-x)Ba0.6
Effect of poling temperature on piezoelectricity of CaZrO3-modified (K, Na)NbO3-based lead-free cera
Sol-gel derived Li-La-Zr-O thin films as solid electrolytes for lithium-ion batteries
High capacity and rate performance of LiNi0.5Co0.2Mn0.3O2 composite cathode for bulk-type all-solid-
Improvement of the recoverable energy storage density and efficiency by utilizing the linear dielect
Synergistic effect of rare-earth elements on the dielectric properties and reliability of BaTiO3-bas
Experimental demonstration of hyperbolic property in conventional material-Ferrite
Strong domain configuration dependence of the nonlinear dielectric response in (K,Na)NbO3-based cera
Electrostatic Field Invisibility Cloak
Large piezoresponse of Na0.5Bi0.5TiO3-K0.5Bi0.5TiO3 thin films prepared via water-based sol-gel meth
Fabrication of high-performance Ba0.95Ca0.05Ti0.85Zr0.15O3 ceramics by aqueous chemical coating meth
Low-temperature sintering and microwave dielectric properties of CaF2-doped MgTiO3 ceramics
A new HDPE/BST polymer-ceramic composite for wireless temperature sensing
Robust CaZrO3-modified (K, Na)NbO3-based lead-free piezoceramics: High fatigue resistance insensitiv
Highly (100)-Oriented Bi(Ni1/2Hf1/2)O-3-PbTiO3 Relaxor-Ferroelectric Films for Integrated Piezoelect
Enhancement of Thermoelectric Performance in Hierarchical Mesoscopic Oxide Composites of Ca3Co4O9 an
Characterization of (100)-oriented 0.63BiMg(1/2)Ti(1/2)O(3)-0.37PbTiO(3) piezoelectric films by a so
Thermo-physical properties of rare-earth hexaaluminates LnMgAl(11)O(19) (Ln: La, Pr, Nd, Sm, Eu and
Optimizing direct magnetoelectric coupling in Pb(Zr, Ti)O-3/Ni multiferroic film heterostructures
Nanodomain Engineered (K, Na)NbO3 Lead-Free Piezoceramics: Enhanced Thermal and Cycling Reliabilitie
Dielectric response and thermally stimulated depolarization current analysis of BaNd1.76Bi0.24Ti5O14
Effect of thickness on the stress and magnetoelectric coupling in bilayered Pb(Zr0.52Ti0.48)O-3-CoFe
Enhanced photocatalysis activity of ferroelectric KNbO3 nanofibers compared with antiferroelectric N
BaTiO3-BiYbO3 perovskite materials for energy storage applications
Thickness-dependent phase boundary in Sm-doped BiFeO3 piezoelectric thin films on Pt/Ti/SiO2/Si subs
Optimal Synthesis of Manganese Oxide/Carbon Sphere Hybrids through a Chemical Deposition Process
Phase transition and piezoelectricity of sol-gel-processed Sm-doped BiFeO3 thin films on Pt(111)/Ti/
The reaction of Li6.5La3Zr1.5Ta0.5O12 with water
Synthesis of complex niobate nanostructures via molten-salt reaction: Effect of ZrO2 on product morp
Ceramic-electrode inter-diffusion of (K, Na)NbO3-based multilayer ceramics with Ag0.7Pd0.3 electrode
Structural and electronic properties of cubic KNbO3 (001) surfaces: A first-principles study
Simultaneously concentrated electric and thermal fields using fan-shaped structure
Effect of PbO excess on the microstructure, dielectric and piezoelectric properties, and energy-stor
Temperature-dependent polarization back-switching and dielectric nonlinearity in PbZr0.4Ti0.6O3 ferr
The microstructure and ferroelectricity of BiScO3-PbTiO3 nanoceramics at morphotropic phase boundari
Mie-resonance-coupled total broadband transmission through a single subwavelength aperture
Influence of sintering temperature on core-shell structure evolution and reliability in Dy modified
Strain-mediated voltage control of magnetism in multiferroic Ni77Fe23/Pb(Mg1/3Nb2/3)(0.7)Ti0.3O3 het
膜/块体结构氧化物复合磁电材料研究进展
Bi(Ni1/2Zr1/2)O-3-PbTiO3 relaxor-ferroelectric films for piezoelectric energy harvesting and electro
Determination of crystallographic orientation of lead-free piezoelectric (K,Na)NbO3 epitaxial thin f
Effect of ethylene glycol on the orientation and magnetic properties of barium ferrite thin films de
Voltage-driven hysteretic changes in magnetization in multiferroic Co/BTO composite thin films
Predicting effective magnetoelectric response in magnetic-ferroelectric composites via phase-field m
Enhanced thermoelectric performance of heavy-metals (M: Ba, Pb) doped misfit-layered ceramics: (Ca2-
High-energy-density dielectric films based on polyvinylidene fluoride and aromatic polythiourea for
Grain boundary region and local piezoelectric response of BiScO3-PbTiO3 nanoceramics prepared by com
Strain-domain structure and stability diagrams for single-domain magnetic thin films
A Novel Approach to the Preparation of a Highly Crystallized BaTiO3 Layer on Ni Nanoparticles
Sol-gel based synthesis of ultrafine tetragonal BaTiO3
Converse magnetoelectric coupling in NiFe/Pb(Mg1/3Nb2/3)O-3-PbTiO3 nanocomposite thin films grown on
THE MULTIFERROIC PROPERTIES OF Bi(Fe1/2Cr1/2)O-3 COMPOUND
Ferromagnetic and photocatalytic behaviors observed in Ca-doped BiFeO3 nanofibres
Fatigue-free unipolar strain behavior in CaZrO3 and MnO2 co-modified (K,Na)NbO3-based lead-free piez
Uniform Coating of BaTiO3-Dy2O3-SiO2 Compound Nano Layer on Ni Particles for MLCC Electrode
Piezoelectric properties of Li, Sb, and Ta co-doped (K,Na)NbO3 ceramics with fine grain size sintere
Photoelectrochemical properties of TiO2/SrTiO3 combined nanotube arrays
Low-temperature sintering of (K,Na)NbO3-based lead-free piezoceramics with addition of LiF
Effect of strain on voltage-controlled magnetism in BiFeO3-based heterostructures
Characterization and microwave dielectric properties of TiO2-modified 0.65CaTiO(3)-0.35Sm(0.9)Nd(0.1
Domain evolution of tetragonal Pb(ZrxTi1-x) O-3 piezoelectric thin films on SrTiO3 (100) surfaces: c
A specially designed Li-H2O2 semi-fuel cell: A potential choice for electric vehicle propulsion
Effect of Pyrolysis Temperature on Sol-Gel Synthesis of Lead-free Piezoelectric (K,Na)NbO3 Films on
Low Temperature Sintering and Enhanced Piezoelectricity of Lead-Free (Na0.52K0.4425Li0.0375)(Nb0.86T
Composition Inhomogeneity due to Alkaline Volatilization in Li-Modified (K, Na)NbO3 Lead-Free Piezoc
High Li ion conductivity in strontium doped Li7La3Zr2O12 garnet
Hierarchically porous Co3O4 hollow spheres with tunable pore structure and enhanced catalytic activi
Dielectric and ferroelectric properties of AgSbO3-modified (Li,K,Na)(Nb,Ta)O-3 lead-free piezocerami
Effect of Mg on the dielectric and electrical properties of BaTiO3-based ceramics
Dielectric response of Mg0.95Ca0.05TiO3 ceramic filled HDPE composites with low dielectric loss
An ultrahigh dielectric constant composite based on polyvinylidene fluoride and polyethylene glycol
Core structures of {110} edge dislocations in BaTiO3
Effect of MgO on microstructure and microwave dielectric properties of 0.84CaTiO(3)-0.16Sm(0.9)Nd(0.
Honeycomb-alumina supported garnet membrane: Composite electrolyte with low resistance and high stre
NiCo-lead zirconium titanate-NiCo trilayered magnetoelectric composites prepared by electroless depo
Facile synthesis of well-dispersed CeO2-CuOx composite hollow spheres with superior catalytic activi
Large d(33) and enhanced ferroelectric/dielectric properties of poly(vinylidene fluoride)-based comp
Core-satellite BaTiO3@SrTiO3 assemblies for a local compositionally graded relaxor ferroelectric cap
Research Progress of Film/Bulk Oxide Magnetoelectric Composites
Polarization Response and Thermally Stimulated Depolarization Current of BaTiO3-based Y5V Ceramic Mu
Performance of Ba0.95Ca0.05Zr0.15Ti0.85O3/PVDF composite flexible films
Phase Structure and Property Evaluation of (Ba,Ca)(Ti,Sn)O-3 Sintered with Li2CO3 Addition at Low Te
Microwave Memristive-like Nonlinearity in a Dielectric Metamaterial
(K, Na) NbO3 based piezoceramics prepared by a two-step calcining and ball milling route
纳米晶钛酸钡粉体的相结构
镍酸镧界面层对锆钛酸铅膜-钴铁氧体陶瓷复合磁电材料性能的影响
Fabrication of Inorganic–Organic Composites for Dental Restorative Materials—A Review
Co/BaTiO3复合薄膜的逆磁电效应
3-1型PZT/air复合材料与PZT/epoxy复合材料的对比研究
SPS烧结制备0-3型CoFe2O4@PZT磁电复合陶瓷
端部双触点型压电驱动器
溶胶-凝胶法制备NASICON型Li1.15Y0.15Zr1.85（PO4）3固态电解质
超细晶钛酸钡基储能陶瓷的性能与微观结构
Li-,Sb-和Ta-共掺杂（K,Na）NbO3陶瓷的低温烧结
Facile synthesis of tremella-like MnO2 and its application as supercapacitor electrodes
核壳结构C@MnO2电极材料的制备及其性能研究
期刊信息
  • 《稀有金属材料与工程》
  • 中国科技核心期刊
  • 主管单位:中国科学技术协会
  • 主办单位:中国有色金属学会 中国材料研究学会 西北有色金属研究院
  • 主编：张平祥
  • 地址：西安市51号信箱
  • 邮编：710016
  • 邮箱：RMME@c-nin.com
  • 电话：029-86231117
  • 国际标准刊号：ISSN：1002-185X
  • 国内统一刊号：ISSN：61-1154/TG
  • 邮发代号:52-172
  • 获奖情况:
  • 首届国家期刊奖,中国优秀期刊一等奖,中国有色金属工业优秀期刊1等奖
  • 国内外数据库收录:
  • 俄罗斯文摘杂志,美国化学文摘（网络版）,荷兰文摘与引文数据库,美国工程索引,美国科学引文索引（扩展库）,英国科学文摘数据库,日本日本科学技术振兴机构数据库,中国中国科技核心期刊,中国北大核心期刊（2004版）,中国北大核心期刊（2008版）,中国北大核心期刊（2011版）,中国北大核心期刊（2014版）,中国北大核心期刊（2000版）
  • 被引量:24715