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滑石粉对PB-1熔融、结晶行为的影响
  • ISSN号:1001-3539
  • 期刊名称:工程塑料应用
  • 时间:2012
  • 页码:71-75
  • 分类:TQ327.8[化学工程—合成树脂塑料工业]
  • 作者机构:[1]青岛科技大学橡塑材料与工程教育部重点实验室,山东青岛266042
  • 相关基金:国家自然科学基金项目(51173089)、山东省科技攻关计划项目(2010GGX10332)
  • 相关项目:MWCNTs等纳米粒子促进PTT结晶成核机理及PTT/PC合金结晶性能调控
中文摘要:

采用双螺杆挤出机熔融制备了聚丁烯-1(PB.1)/滑石粉复合材料,研究了滑石粉含量对PB.1熔融及结晶行为的影响。结果表明,滑石粉显著促进了PB-1的结晶过程,其成核能力在滑石粉质量分数为1%时最佳。非等温结晶动力学研究表明,在滑石粉的实验用量范围内(1%-10%),要达到相同的结晶度,PB-1/滑石粉复合材料的完成温度明显高于纯PB-1的完成温度。当滑石粉质量分数为1%~5%时,要达到相同的结晶度,PB-1/滑石粉所需的时间明显比纯PB.1短;当用量为7%时稍短;当用量为10%时又稍长。但滑石粉不影响PB-1的依热成核方式和三维生长机制。偏光显微镜结果表明滑石粉对PB-1的异相成核作用显著。广角X射线衍射研究表明滑石粉阻碍了PB-1由晶型Ⅱ向晶型Ⅰ的转变过程,使晶型转变变缓。

英文摘要:

The polybutylene-1 / talcum ( PB-I / talcum ) composites were prepared by twin-screw extruder, and effects of talcum on the melting and crystallization behaviors of PB-1 were investigated. The results showed that the crystallization process of PB-1 was accelerated by talcum. Talcum acted as a nucleation agent to PB-1 's crystallization and its nucleation effect was optimum when its content was 1%.The investigations for the non-isothermal crystallization kinetics of PB-1 and PB-1 /talcum indicated that the temperature to reach a given crystallinity for PB-1 /talcum was much higher than that of pure PB-1 at the experimental talcum contents ( 1%- 10% ). Moreover,the time to reach a given crystallinity for PB-1/talcum was much shorter than that of pure PB-1 as talcum content was 1% - 5%, and it was a little shorter as talcum was 7%, whereas it changed a little longer as talcum was 10%. The thermal nucleation mode and three dimensional growth mechanism of PB-1 's crystallization were remained unchanged even though talcum was presented. The polarizing optical microscope results indicated that the nucleation effect of talcum on the crystallization of PB-1 was markedly, whereas the WAXD results showed that the transition process of crystalline form Ⅱ to form Ⅰ for PB-1 was retarded by the presence of talcum.

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期刊信息
  • 《工程塑料应用》
  • 中国科技核心期刊
  • 主管单位:中国兵器工业集团公司
  • 主办单位:中国兵器工业集团第五三研究所、中国工程塑料工业协会
  • 主编:王金立
  • 地址:山东济南市天桥区无影山田庄东路3号
  • 邮编:250031
  • 邮箱:epa@epa1973.com
  • 电话:0531-85878057
  • 国际标准刊号:ISSN:1001-3539
  • 国内统一刊号:ISSN:37-1111/TQ
  • 邮发代号:24-42
  • 获奖情况:
  • 首届国家期刊奖,第二届全国优秀科技期刊一等奖,中国期刊方阵“双高”期刊
  • 国内外数据库收录:
  • 美国化学文摘(网络版),日本日本科学技术振兴机构数据库,中国中国科技核心期刊,中国北大核心期刊(2004版),中国北大核心期刊(2008版),中国北大核心期刊(2011版),中国北大核心期刊(2014版),中国北大核心期刊(2000版)
  • 被引量:12993