本文基于电化学反应原理及热力学分析方法,研究固体氧化物燃料电池非热力循环产功机理。基于电化学反应原理,建立了SOFC性能分析模型,研究了SOFC电池性能与电化学参数之间的变化关系,从而揭示了SOFC化学能直接转变为电能的机理;分析了热力学参数及电化学参数对SOFC系统性能的影响规律,提出改善SOFC电池性能的途径,并揭示了通过SOFC与先进热力循环系统集成进一步提高动力系统性能的潜力。本文研究成果为开拓研究高效SOFC复合动力系统提供有益的参考。
Based on the principle of electrochemical reaction and analysis method of thermodynamics, this paper studies the power generation mechanism of Solid Oxide Fuel Cell (SOFC). On the base of the principle of electrochemical reaction, SOFC system modes were established, effects of electrochemical parameters on the system performance of SOFC were analyzed and the power generation mechanism of SOFC from chemical energy to electricity energy by a non-thermodynamic mode was revealed. The -effects of thermodynamic parameters on the SOFC system performance were also studied. The main ways of improving the SOFC system performance are proposed and the potential of enhancing the total hybrid power system performance by integrating SOFC with advanced thermal cycle system are revealed. Above research achievements will provide valuable reference for further study on SOFC hybrid power system with high efficiency.