采用磷酸二氢铵、重烧镁砂、硼砂和模拟放射性焚烧灰制备水泥固化体,对含有模拟放射性焚烧灰的磷酸镁水泥固化体进行了性能研究,通过强度分析、抗冲击性能以及浸出率测试,分析了磷酸镁水泥对模拟放射性焚烧灰的固化性能,通过x射线衍射和扫描电子显微镜对样品物相和微观结构进行了研究,并测试了浸出率。结果表明:磷酸镁水泥具有良好的固化性能,在满足国家标准要求情况下,所制备的试样对含Cs和Sr的模拟焚烧灰包容量可达40%(质量分数),对Cs^+的42d浸出率为2.6×10^-4cm/d,sr^2+的42d浸出率为1.1×10.4cm/d,Cs^+和sr2^+的42d累计浸出值分别为0.20cm和0.07cm,均优于国家标准相关要求。
Magnesium phosphate cement (MPC) was prepared by using ammonium dihydrogen phosphate, dead-burned magnesium oxide and borax as raw materials. The solidification performance of MPC was evaluated by compressive strength, anti-shocking test and leaching properties of the as-prepared samples. The phases and microstructure of samples were analyzed by X-ray diffraction and scanning electron microscopy, respectively. The results show that MPC has a superior performance for solidifying the simulated ra- dioactive incineration ash. The samples could solidify the incineration ash (with Sr and Cs) of 〉40% (in mass fraction). The leaching rates of Cs and Sr obtained were 2.6 × 10^-4 cm/d and 1.1× 10^-4 crn/d, respectively. And their cumulative leaching fraction of 42 d were 0.20 cm and 0.07 cm, respectively. They were both lower than that of leaching rate required by the national standard.