采用微波辅助共沉淀法制备紫外发射荧光粉Sr1-xCO3:xCe^3+,并利用扫描电镜、激光粒度测试、X射线衍射和荧光光谱等分析手段分别对样品SrCO3:Ce^3+的形貌、粒径、物相和发光性能进行表征。结果表明:掺杂Ce^3+作为发光中心进入到纯斜方晶系碳酸锶晶格中。没有导致晶体结构的变化;样品呈类球状分布,粒径范围3—8μm。中值粒径也萨5.518μm;以254、327nm波长激发均产生峰值位于354、378nm的宽发射谱带,位于近紫外发射区,可以应用于黑光灯等;随着Ce^3+离子掺杂浓度的增大,发光强度先增加后减小,其淬灭浓度为1.5%(摩尔分数);根据Dexter理论得出样品的浓度猝灭机理为电偶极-四极相互作用。
The Ce^3+-doped strontium carbonate phosphor was synthesized via co-precipitation route by microwave assisted. The phosphor powders were characterized by scanning electron microscopy (SEM), laser particle size analyzer, X ray diffraction (XRD) and photoluminescence and photoluminescence excitation (PL-PLE) spectrum. The results showed that Ce^3+acted as a luminescent center probe into the single orthorhombic phase SrCO~ not result in the crystal structure changed. The sample particles were in approximate spherical structure with size of 3-8 μm, median diameter d50=5.518 μm. Under the 254, 327 nm ultraviolet lamp, the PL spectrum showed a broadband absorption center in 354, 378 nm, which located in near ultraviolet emitting region and could be used in black light lamps etc.The luminescent intensities increased with the increasing Ce^3+ concentration, and then decreased because of concentration quenching. The optimal concentration of Ce^3+ was 1.5% (molar fraction). The concentration self-quenching mechanism was electric dipole-quadruple interactions.