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聚四氟乙烯和石墨对聚醚酰亚胺摩擦学性能的影响
  • ISSN号:0251-0790
  • 期刊名称:《高等学校化学学报》
  • 时间:0
  • 分类:O632[理学—高分子化学;理学—化学]
  • 作者机构:[1]吉林大学化学学院,麦克德尔米德实验室,长春130012
  • 相关基金:国家“九七三”计划项目(批准号:2010CB631100)和国家科技支撑计划项目(批准号:2011BAA06803)资助.
中文摘要:

将聚四氟乙烯( PTFE)和石墨两类减摩耐磨填料填充到聚醚酰亚胺( PEI)中,表征其摩擦性能,利用扫描电子显微镜分析了磨损表面的显微结构,并分析了磨损机制.研究结果表明, PTFE和石墨的填充明显改善了PEI的摩擦磨损性,摩擦系数降低到0.3以下(纯PEI的摩擦系数为0.41),磨损率降低了3个数量级.在PTFE体系中, PTFE质量分数为10%时, PEI基共混材料的摩擦系数最低为0.23;而在质量分数为15%的石墨体系中, PEI基共混材料摩擦系数最低为0.27.磨损率随着填料含量的增加而逐渐下降,在填料质量分数为20%之后,摩损率下降平缓.因此PTFE和石墨的填充对PEI的摩擦学性能起到了很好的改善作用,而且PTFE比石墨的改善效果更优益.共混物的机械性能测试结果表明,在填料质量分数为5%~15%时,共混物具有良好的机械性能.

英文摘要:

The tribological performances of polyetherimide( PEI) composite materials filled with polytetraflu-oroethylene( PTFE) and graphite were evaluated on UMT-2 friction and wear tester, respectively. The micro-structures of worn surfaces, cross-sections of the PEI composite were examined with scanning electron micro-scope( SEM) , and wear mechanism was analyzed. The result showed that PEI composite filled with PTFE and graphite were improved significantly on friction and wear properties. The friction coefficient is reduced to below 0. 3(the friction coefficient of pure PEI is 0. 41), the wear rate is reduced by 3 orders of magnitude. When filled with 10%PTFE in composites PTFE system, the friction coefficient of the composites is lowest, and the friction coefficient of the graphite counterpart is lowest in 15% graphite content. The lowest friction coefficient is 0. 23 and 0. 27. For the wear rate, PEI composite materials filled with PTFE and graphite are both de-creased with the content increasing respectively. Consequently, compared with the PEI composite materials filled with graphite, the PEI composite materials filled with PTFE has more excellent tribological performance and mechanical behavior. The mechanical behavior of two kinds of the PEI composites was also measured, such as tensile strength, bending strength, impact strength and Rockwell hardness. The results show that, when the mass fraction of 5%—15%, which is the best tribological performance improvement in addition, comprehensive mechanical properties of blends of materials is still good.

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期刊信息
  • 《高等学校化学学报》
  • 北大核心期刊(2011版)
  • 主管单位:中华人民共和国教育部
  • 主办单位:吉林大学 南开大学
  • 主编:周其凤
  • 地址:吉林大学南胡校区
  • 邮编:130012
  • 邮箱:cjcu@jlu.edu.cn
  • 电话:0431-88499216
  • 国际标准刊号:ISSN:0251-0790
  • 国内统一刊号:ISSN:22-1131/O6
  • 邮发代号:12-40
  • 获奖情况:
  • 首届及第二届国家期刊奖,连续两届“百种中国杰出学术期刊”,中国期刊方阵“双高”期刊
  • 国内外数据库收录:
  • 俄罗斯文摘杂志,美国化学文摘(网络版),荷兰文摘与引文数据库,美国工程索引,美国科学引文索引(扩展库),日本日本科学技术振兴机构数据库,中国中国科技核心期刊,中国北大核心期刊(2004版),中国北大核心期刊(2008版),中国北大核心期刊(2011版),中国北大核心期刊(2014版),英国英国皇家化学学会文摘,中国北大核心期刊(2000版)
  • 被引量:50676