我们采用脉冲激光沉积法,在SrTiO3(001)衬底上以La0.7Sr0.3MnO3作为底电极,制备得单相的0.95(Na0.49K0.49Li0.02)(Nb0.8Ta0.2)-0.05CaZrO3外延薄膜.采用X射线衍射、X射线光电子能谱,电滞回线和介电常数测试分别表征了LKNNT-CZ薄膜的微观结构、表面元素价态和铁电/介电性能.结果表明:(1)制备得到的LKNNT-CZ薄膜的元素组成与靶材相同;(2)在4伏到10伏内均可以获得线型良好且饱和的电滞回线,当驱动电压为10V时,薄膜的剩余极化达到12.4μC/cm2,矫顽电场为102.3kV/cm;(3)薄膜在1kHz频率下的介电常数高达1185.
Single phase and epitaxial 0. 95(Na0.49K0.49Li0.02)(Nb0.8Ta0.2)-0. 05CaZrO3 (LKNNT-CZ) piezoelectric thin films are successfully fabricated on La0. 7 Sr0. 3 MnO3 coated SrTiO3 (001) substrates by pulsed laser deposition. The microstructures, surfaces, ferroelectrie and dielectric properties are intensively investigated with high-resolution X-ray diffraction (XRD), X-ray photoelectron spectra (XPS), P-E loops and dielectric constant measurements. It is found the epitaxial LKNNT-CZ films show well saturated ferroelectrie hysteresises with the drive voltage ranging from 4 V to 10 V. The film contains a typical dielectric constant of 1185 at 1 kHz, a remnant polarization (P,) of 12. 4 μC/cm^2 and a coercive field (Ec) of 102. 3 kV/em under 10 V.