采用旋涂法制备了若丹明6G(Rh6G)和若丹明B(RhB)两种染料掺杂的DNA-CTMA复合薄膜,并通过对薄膜的表面形貌、紫外/可见/红外吸收光谱、荧光光谱特性的测量,表征了薄膜的成膜质量及光谱特性。通过Nd:YAG脉冲激光器的倍频光激发,研究了不同比例荧光染料掺杂DNA—CTMA薄膜的放大自发辐射(ASE)现象并做了理论解释。实验结果表明,在波长为532nm的脉冲激光抽运下,Rh6G/RhB/DNA-CTMA薄膜的发射谱出现了明显的窄化现象,而且比单一染料掺杂DNA—CTMA薄膜的发射谱呈现出较大的光谱调谐范围,是一种较好的有机聚合物激光材料体系。
The fluorescent dye Rhodamine-6G (Rh6G) and Rhodamine-B (RhB) doped DNA-CTMA thin films are prepared by spin-coating technology. The quality and optical spectra properties of Rh6G/RhB/DNA-CTMA thin films are characterized by the measurements of surface morphology, UV/vis/infrared absorption spectra and fluorescence spectra. The amplified spontaneous emission (ASE) of dye-doped DNA-CTMA thin films with different dye contents was researched experimentally by pumping of Nd: YAG pulse laser at wavelength of 532 nm, and is explained theoretically. The experimental results show that the narrowing phenomenon of emission spectra of Rh6G/RhB/DNA- CTMA thin films is very clear and strong. Compared with single dye doped DNA-CTMA thin films, the co-doped Rh6G/RhB/DNA-CTMA thin film is a potential candidate as an organic polymer laser material because it exhibits more wider tuning range of the ASE spectrum.