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粉煤灰活性炭处理含铜废水的性能
  • ISSN号:0254-6108
  • 期刊名称:《环境化学》
  • 时间:0
  • 分类:X773[环境科学与工程—环境工程]
  • 作者机构:[1]上海大学环境与化学工程学院,上海200444, [2]江西理工大学资源与环境工程学院,赣州341000, [3]华东交通大学土木建筑学院,南昌330013
  • 相关基金:国家自然科学基金重点项目(41130526); 教育部固体废物处理与资源化重点实验室开放课题(10zxgk02)资助
中文摘要:

为了研究粉煤灰活性炭的吸附性能,以原粉煤灰和纯活性炭作对照,比较3种吸附剂在不同时间、pH和投加量下处理含Cu(Ⅱ)废水的性能.结果表明,在pH 5,吸附时间60 min的条件下,纯活性炭、粉煤灰活性炭和粉煤灰对含Cu(Ⅱ)废水的去除率依次为100%、97%和78.7%,粉煤灰活性炭吸附性能接近纯活性炭.Cu饱和的粉煤灰活性炭,用0.2 mol.L-1浓度的HCl清洗解吸效果最好.在饱和吸附和解吸重复10次后,再生粉煤灰活性炭的吸附容量下降20%,接近活性炭的18%,充分说明粉煤灰活性炭有较好的可再生性.粉煤灰制成粉煤灰活性炭,用于含金属废水的治理,不仅效果好、成本低,还是粉煤灰资源化的重要途径,有广阔的应用前景.

英文摘要:

Coal ash released from power plants contains unburned carbon, which can be extracted and made into activated carbon through the flotation-concentration method. In order to study its adsorbing capability, the experiment of using this activated carbon to remove Cu (Ⅱ) from Cu-containing wastewater under different reaction time, pH and inputs, was carried out, with the original coal ash and pure activated carbon being served as controls. The results showed that the rates of Cu (Ⅱ) removal from the Cu-containing wastewater treated with the pure activated carbon, the activated carbon made from coal ash and the original coal ash are 100%, 97% and 78.7%, respectively, under the reaction condition of pH 5 and 60 minutes, which suggests that the adsorption capability of the activated carbon made from coal ash is close to that of the pure activated carbon. Using HC1 solution to desorb Cu (Ⅱ) from the Cu-saturating activated carbon, the concentration of 0. 2 mol- L^-1 is the most effective. The adsorbing capability of the regenerated activated carbon made from coal ash decreases by 20% after alternating between the saturating adsorption and desorption of Cu (Ⅱ) for ten times, which is close to that of the pure activated carbon by 18%. This fully suggests that the activated carbon made from coal ash also has the advantage of good reproducibility. Therefore, using the activated carbon made from coal ash for the recovery of metal-containing wastewater not only has perfect effects, but also is low cost. Moreover, this is also a good way for the reclamation of coal ash and hence has a promising future.

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期刊信息
  • 《环境化学》
  • 北大核心期刊(2011版)
  • 主管单位:中国科学院
  • 主办单位:中国科学院生态环境研究中心
  • 主编:郭良宏
  • 地址:北京2871信箱
  • 邮编:100085
  • 邮箱:hjhx@rcees.ac.cn
  • 电话:010-62923569
  • 国际标准刊号:ISSN:0254-6108
  • 国内统一刊号:ISSN:11-1844/X
  • 邮发代号:82-394
  • 获奖情况:
  • 国内外数据库收录:
  • 俄罗斯文摘杂志,美国化学文摘(网络版),美国剑桥科学文摘,日本日本科学技术振兴机构数据库,中国中国科技核心期刊,中国北大核心期刊(2004版),中国北大核心期刊(2008版),中国北大核心期刊(2011版),中国北大核心期刊(2014版),英国英国皇家化学学会文摘,中国北大核心期刊(2000版)
  • 被引量:27127