以对(邻)苯二甲醛和4-胺基苯基二苯胺为原料,合成了两种含三苯胺基团的席夫碱化合物,两种化合物结构经红外光谱、元素分析、电喷雾质谱进行了表征。运用紫外-可见吸收光谱和荧光发射光谱研究了化合物的光学性质。结果表明直线型化合物1的紫外和荧光光谱和V型化合物2相比发生了较大程度的红移。
Two triphenylamine-contained Schiff bases were obtained by reaction of p-phthalaldehyde(o-phthalaldehyde) and 4-aminophenyl diphenylamine. The structures were characterized by IR, elemental analysis and ESI-MS. The optical proper- ties were studied by UV absorption spectra and fluorescence spectra. The results showed that the absorption and fluorescence spectra of 1 exhibit obvious trend of red-shift compared with those of 2.