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优越磁性能的SrFe12O19微管的模板法制备
  • 期刊名称:无机材料学报,2009,24(4): 717-720
  • 时间:0
  • 分类:O614[理学—无机化学;理学—化学] TQ586[化学工程—精细化工]
  • 作者机构:[1]中北大学理学院化学系,太原030051
  • 相关基金:国家自然科学基金(20571066,20871108)
  • 相关项目:高效吸波纳米掺杂铁氧体/高分子复合材料的软化学合成与性能
中文摘要:

脱脂棉作模板,采用溶胶-凝胶法制备并在不同温度下煅烧后制得了SrFe12O19微管,并用原溶胶-凝胶法制得了六角型纳米SrFe12O19.利用X射线衍射技术(XRD)﹑扫描电子显微镜(SEM)、透射显微镜(TEM)对样品的物相﹑形貌和粒径进行表征,并利用振动样品磁强计(VSM)对样品进行磁性能研究.结果表明:借助脱脂棉模板,采用溶胶凝胶法制备了外径在8-13μm之间,壁厚在1-2μm之间的SrFe12O19微管,与原溶胶凝胶法制备的六角型SrFe12O19相比,SrFe12O19微管的矫顽力提高了30%左右,比饱和磁化强度和剩余磁化强度提高了20%左右,最终制得了矫顽力、比饱和磁化强度和剩余磁化强度分别为47.2kA/m、70.1A·m^2/kg和42.4A·m^2/kg的纯六方磁铅石型SrFe12O19微管,并对微管的形成以及磁性能提高的原因做了解释.

英文摘要:

The strontium ferrite microtubules were prepared by the solgel method using the absorbent cotton as template and calcined at different temperatures.And the hexagonal nano-SrFe12O19 was prepared by prime sol-gel method.The phase,morphology and particle diameter of samples were studied by XRD,SEM and TEM.The magnetic properties of samples were tested by VSM.It is found that the strontium ferrite microtubules are obtained through the absorbent cotton template.The microtubules is fabricated with the external diameter of 8μm to 13μm and the wall thickness of 1μm to 2μm.The coercive force and magnetization of the strontium ferrite microtubules are improved by 30%,20%,respectively.The coercive force,the specific saturation magnetization and residual magnetization of the microtubules are 547.2kA/m,70.1A·m^2/kg and 42.4A·m^2/kg,respectively.The formation mechanism of the microtubules are dicussed.

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