欢迎您！东篱公司
退出
-
申报数据库
-
立项数据库
-
成果数据库
-
项目获奖数据库
中文摘要：
用舒克紧束缚法计算了一种新型香蕉型液晶1,3-phenylene bis[-4-（4’-nonyloxy）phenyliminomethyl]benzoate的电子结构，结果表明：LUMO和HOMO的能量差别主要是受到香蕉型液晶的中心核、桥键（—COO—）的影响，而烷基尾对香蕉型液晶电子结构的影响不大；在6种可能跃迁中，只有能量最低的两种（π→π，n→π）在200-800nm可见光范围内是经常发生的。对于这种香蕉型液晶，电子激发主要发生在4．0eV（310nm）和1．7eV（730nm）处。
英文摘要：
The electronic structures of the banana-shaped liquid crystal 1,3-phenylene bis E4-（4＇-nonyloxy） phenyliminomethyl] benzoate were calculated with Huckel tight-binding method. The effects of the central core, the linkages and the alkyl tails in the two-branched legs of the banana-shaped liquid crystal were discussed. Among the six transitions outlined, only the two lowest energy ones （π→π,n→π） are often achieved by the energies available in the 200-800 nm spectrum. Energetically favoured electron excitation will take place at 4.0 （310 nm） and 1.7 eV （730 nm）, respectively, for the studied molecule.
同期刊论文项目
同项目期刊论文
Synthesis and mesomorphic properties of three-ring containing bent-core liquid crystal 1,3-phenylene
Mesomorphic properties of three-benzene-ring containing bent-core liquid crystals 1,3-phenylene-bis[
Synthesis and mesomorphic properties of three-benzene-ring containing bent-core liquid crystal 1,3-p
Periodically birefringent thin films grown out of the isotropic phase of a bent-core banana-shaped l
Dependence of optical properties of UV-curable sealant on amount of catalyst N, N-dimethylbenzylamin
Concentration-dependent light scattering in lyotropic liquid crystal formed by sodium dodecyl sulfon
Influence of cooling rates on phase transitions of bent-core liquid crystal 1,3-phenylene-bis[4-(hex
Effects of red and green laser irradiations on the optical properties of an azo-containing bent-core
Correlation of excitation-wavelength dependent photoluminescence with the fractal microstructures of
Mechanical Grinding: An Effective Method to Control the Conductivity of p-toluene Sulfonic Acid Dope
Origin of the Deep Blue Photoluminescence of a Liquid Crystalline Polymer Poly[(4-Hexylcarbonyl-Biph
期刊信息
位置：