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锰掺杂钴铁氧体粉体的磁性能和介电性能
  • 期刊名称:金沈贤,钟智勇,张怀武, 锰掺杂钴铁氧体粉体的磁性能和介电性能, 硅酸盐学报 35(7), 838-
  • 时间:0
  • 分类:TM271[电气工程—电工理论与新技术;一般工业技术—材料科学与工程] TM277[电气工程—电工理论与新技术;一般工业技术—材料科学与工程]
  • 作者机构:[1]电子科技大学微电子与固体电子学院,成都610054
  • 相关基金:国家自然科学基金(60490296,60671029,90306015)资助项目.
  • 相关项目:纳米级光-磁混合非连续记录介质的制备和记录特性研究
中文摘要:

采用传统陶瓷工艺制备了Mn掺杂非正分Co铁氧体C0.07MnxFe2.3-xO4粉体样品。用X射线衍射仪、振动样品磁强计及阻抗分析仪研究样品的结构、磁性能和介电性能。研究表明:样品均以单相尖晶石结构存在,掺Mn降低了材料Curie温度,也使矫顽力和饱和磁化强度减小,Mn掺量x=7时,材料的curie温度、矫顽力和饱和磁化强度分别为314.5℃,6.9×10^3A/m和13.1×10^3A/m,均小于未掺Mn时的值:材料的介电性能也与Mn掺量有关,在一定的频率下,随Mn掺量的增加电阻率先减小后增大,而介电常数和介电损耗则先增大后减小。

英文摘要:

Mn-doped non-stoichiometric cobalt ferrite Co0.7MnxFe2.3-xO4 powders were prepared by traditional ceramic techniques. The structure, magnetic properties and dielectric properties were characterized using an X-ray diffractometer, a vibrating sample magnetometer and an impedance analyzer. The research revealed that all of the samples has a single spinel phase, Mn doping decreased the Curie temperature of cobalt ferrite while reducing the coercivity and magnetization at the same time. With a dosage of Mn x=0.7, the Curie temperature, coercivity and magnetization were 314.5 ℃, 6.9 × 10^3 A/m and 13.1 ×10^3 A/m, respectively, smaller than that of materials without Mn dosage. It also revealed that the dielectric properties of the material also change with Mn dosage; the resistivity first decreases and then increases with increasing Mn dosages under certain frequencies while the dielectric constant and dielectric loss are opposite.

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