用定量加入NaOH的方法高产率地合成了烷氧基稀土钠簇合物SmNa8(O^t Bu)10(OH),并对其进行了X射线晶体结构鉴定.此外,将其对芳醛的Tishchenko反应的催化活性进行了初探.
The lanthanide-sodium alkoxide cluster SmNa8 (O^t Bu)10 (OH) was synthesized in high yields by adding a certain amount of NaOH, and its structure was confirmed by X-ray. Moreover, its catalytic activity was tested for the Tishchenko reaction of aromatic aldehydes.