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富氢重整气中微量一氧化碳的选择性催化甲烷化
  • 期刊名称:天然气化工
  • 时间:0
  • 页码:58-62
  • 语言:中文
  • 分类:O643[理学—物理化学;理学—化学]
  • 作者机构:[1]华南理工大学化工与能源学院,广州510640
  • 相关基金:国家自然科学基金(20576023),广东省自然科学基金(06025660)
  • 相关项目:甲醇燃料电池电动车富氢气体中CO的选择性氧化
中文摘要:

质子交换膜燃料电池已成为汽油内燃机动力最具竞争力的洁净取代动力源,其所用的富氢重整气中微量的CO对电池电极的毒化作用会严重降低燃料电池的效率。文章对采用选择性甲烷化法去除富氢重整气中微量CO的催化剂的研究现状进行了综述,简述了载体和改性助剂对催化剂性能的影响,并阐述了CO和CO2甲烷化过程机理的差异。

英文摘要:

Proton Exchange Membrane Fuel Cell (PEMFC) would be the most competitive clean substitute power source for the gasoline engine power, while the electrodes of the fuel cell is easily poisoned by the trace CO contained in the hydrogen-rich reformed gases, which would reduced PEMFC efficiency greatly. The Catalysts for se- lective methanation of trace CO in hydrogen-rich reformed gases were reviewed. The effects of supports and additives on the activities of catalysts were introduced briefly, and the differences of the mechanism of CO and CO2 methanation were also presented in detail.

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