位置:成果数据库 > 期刊 > 期刊详情页
负载型钾基CO2吸收剂的结构表征和碳酸化反应特性
  • 期刊名称:化工学报
  • 时间:0
  • 页码:1800-1805
  • 语言:中文
  • 分类:TQ534.9[化学工程—煤化学工程] TD775[矿业工程—矿井通风与安全]
  • 作者机构:[1]东南大学能源与环境学院,江苏南京210096
  • 相关基金:国家自然科学基金项目(50876021);国家重点基础研究发展计划项目(2006CB705806);江苏省普通高校研究生科研创新计划项目(CX08B_141Z);东南大学优秀博士学位论文基金项目(YBJJ0825).
  • 相关项目:碱金属基吸收剂干法脱除二氧化碳机理研究
中文摘要:

引言 CO2减排已成为21世纪人类面临的焦点问题。而在我国燃煤电厂作为CO2排放量最大、排放最集中的化石燃料燃烧场所,对其进行CO2减排技术的研究和开发势在必行。CO2减排技术主要分燃烧前脱碳、化学链循环、纯氧燃烧和燃烧后捕集4大类^[1-4]。

英文摘要:

The structure identification and carbonation characteristics of several potassium-based supportecl sorbents for CO2 capture were investigated with TGA, XRD, XRF, SEM and N2 adsorption method. Potassium-based sorbents were prepared by impregnation with potassium carbonate on supports, such as cocoanut activated charcoal (AC1), coal active carbon (AC2), silica gel (SG) and diatomite (DT) using the iso-volume impregnation method. The results showed that the K2COs loading amounts of AC1, AC2, SG and DT were 24.1%, 22.5%, 21.7% and 19.1% respectively. The surface area and pore volume of K2CO3/AC1 and K2CO3/AC2 were larger than others. In contrast, those of K2CO3/DT were small. For K2CO3/SG, pore volume was large but surface area was small. K2CO3/AC1 and K2CO3/ AC2 showed excellent carbonation capacity. However, the carbonation capacities of K2CO3/SG and K2CO3/DT were low. The difference in carbonation capacity of those sorbents were attributed to the difference in pore structure, leading to different supported sorbents.

同期刊论文项目
期刊论文 20 会议论文 2 专利 6
同项目期刊论文