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南海中华小尖柳珊瑚Muricella sinensis化学成分的研究
  • 期刊名称：有机化学
  • 时间：0
  • 页码：1264-1267
  • 语言：中文
  • 分类：O614.6[理学—无机化学;理学—化学] Q959.12[生物学—动物学]
  • 作者机构：[1]广州市药品检验所,广州510160, [2]中国科学院上海药物研究所国家新药研究重点实验室,上海201203
  • 相关基金：国家海洋863计划（Nos.2006AA09Z447,2006AA09Z412,2007AA09Z447）、国家自然科学基金（Nos.20572116,30730108,20721003）、上海市科委基础研究（Nos.07XD14036,06DZ22028）和中国科学院重点（No.KSCX2-YW-R-18）资助项目.
  • 相关项目：南海软体动物及其食源生物的化学，化学生态学和生物活性研究
作者： 郭跃伟|李震宇|严小红|
关键词： 柳珊瑚, Muricella, SINENSIS, Eunicellane型二萜, gorgonian, Muricella sinensis, eunicellane diterpenoid
中文摘要：

从采自中国南海的中华小尖柳珊瑚（Muricella sinensis）中分离得到了1个新的Eunicellane型二萜，命名为sinensin（1），和6个已知化合物：13-去乙酰氧基calicophirin B（2），calicophirin B（3），calicophirin C（4），astrogorgin（5），calicoferol E（6）和calicoferol B（7），这些化合物的结构是经波谱学实验（^1H NMR，^13C NMR，HMQC，HMBC，COSY和NOESY）并与文献报道的数据对照而确定的．

英文摘要：

A new eunicellane diterpenoid, named sinensin （1）, together with six known compounds, namely 13-deacetoxyl decalicophirin B （2）, calicophirin B （3）, calicophirin C （4）, astrogorgin （5）, calicoferol E （6） and calicoferol B （7）, has been isolated from the gorgonian Muricella sinensis from the South China sea. Their structures were elucidated on the basis of spectroscopic analysis and by comparison with the data reported in literature.

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