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刮膜式分子蒸馏器内传质的数值模拟
  • ISSN号:1003-9015
  • 期刊名称:《高校化学工程学报》
  • 时间:0
  • 分类:O621.256.7[理学—有机化学;理学—化学]
  • 作者机构:[1]天津大学化工学院,天津300072, [2]台州学院医药化工学院,台州318000
  • 相关基金:国家自然科学基金(Nos.21106090,21176170)资助项目
中文摘要:

Michael加成反应是有机合成领域一类非常重要的反应.随着人们环保意识的增强和对绿色化学研究的深入,环境友好型Michael加成取得了诸多成功.综述了近5年来离子液体、酶催化、负载固相催化、聚乙二醇(PEG)等参与的Michael加成反应的研究进展.着重分析了反应体系的高效性、催化剂可能的催化反应机理以及催化剂的循环使用性,并以此对环境友好型Michael加成的发展做出了展望.

英文摘要:

Michael addition is one kind of important reaction in the organic field. With the enhancement of environmental awareness and the depth of green chemistry research, environmentally-friendly Michael addition has made many successes. The research progress over the past 5 years in the Michael addition involving ionic liquids, enzyme catalysis, solid phase supported catalysis and polyethylene glycol(PEG) is reviewed. This paper is consisted of six parts, focusing on the efficiency of the reaction system, the probable catalytic mechanism and the recycle of the catalyst. In the first part, a brief introduction is given. Then the Michael addition used the ionic liquid as catalyst or/and solvent is elaborated. In this part, acidic ionic liquid, basic ionic liquids and chiral ionic liquid are described, respectively. As a mild catalyst, enzymes are described in the third part. The solid phase supported catalysis has been used in many reaction without exception to Michael addition. So, in the fourth part, the catalysts of polymer supported, silica-supported and superparamagnetic nano supported are stated. Following, the successful use of polyethylene glycol(PEG) as a green solvent is presented. Finally, the conclusion, the existing problems of these green technologies and the prospect are summarized.

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期刊信息
  • 《高校化学工程学报》
  • 北大核心期刊(2011版)
  • 主管单位:国家教育部
  • 主办单位:浙江大学
  • 主编:陈纪忠
  • 地址:杭州浙大路38号浙江大学玉泉校区化工系
  • 邮编:310027
  • 邮箱:gxhgxb@zju.edu.cn
  • 电话:0571-87951235
  • 国际标准刊号:ISSN:1003-9015
  • 国内统一刊号:ISSN:33-1141/TQ
  • 邮发代号:
  • 获奖情况:
  • 2000年获浙江省科技期刊编辑学会颁发的“1999-200...,中国期刊方阵“双效”期刊
  • 国内外数据库收录:
  • 俄罗斯文摘杂志,美国化学文摘(网络版),荷兰文摘与引文数据库,美国工程索引,美国剑桥科学文摘,日本日本科学技术振兴机构数据库,中国中国科技核心期刊,中国北大核心期刊(2004版),中国北大核心期刊(2008版),中国北大核心期刊(2011版),中国北大核心期刊(2014版),中国北大核心期刊(2000版)
  • 被引量:14205