欢迎您！东篱公司
退出
-
申报数据库
-
立项数据库
-
成果数据库
-
项目获奖数据库
中文摘要：
以N-苯基邻氨基苯甲酸与二丁基氧化锡反应,制得新配合物{[（n-C4H9）2Sn（0.5·O2CC12H10N）（0.5·CH3O）]2O}2。通过元素分析、红外光谱和核磁共振氢谱对其结构进行了表征,用X-射线单晶衍射测定了配合物的晶体结构。该配合物晶体属于三斜晶系,空间群为P-1,晶胞参数a=1.173（2）nm,b=1.256（2）nm,c=1.329（2）nm,α=82.29（3）°,β=71.83（3）°,γ=65.36（3）°,V=1.690（5）nm3,Z=1,μ=1.509 mm-1,Dc=1.425 Mg.m-3,F（000）=736,R=0.056 9,wR=0.1589,GOF=1.074。测试结果表明,它是以Sn2O2四元环为中心,中心对称的二聚体结构。内、外环锡原子均为五配位的畸变三角双锥构型。
英文摘要：
Organotin（Ⅳ） compound {[（n-C4H9）2Sn（0.5·O2CC12H10N）（0.5·CH3O）]2O}2 was synthesized by the reaction of n-dibutyltin oxide with N-phenylanthranilic acid.The compound was characterized by elemental analysis,IR and 1H NMR analyses.The crystal structure was determined by X-ray single crystal diffraction method.The result indicates that crystal belongs to triclinic,space group P-1 with a =1.173（2） nm,b = 1.256（2） nm,c= 1.329（2） nm,α = 82.29（3）°,β = 71.83（3）°,γ = 65.36（3）°,V = 1.690（5） nm3,Z = 1,μ= 1.509 mm-1,Dc = 1.425 Mg·m-3,F（000） =736,R = 0.056 9,wR = 0.158 9,GOF = 1.074.The complex is a centrosymmetric structure mode with a four-member central endo-cyclic Sn2O2 unit in which two bridged oxygen atoms both connect with an exo-cyclic tin atom.The endo-cyclic tin atoms and the exo-cyclic tin atoms are all five-coordination and have coordination geometry of distorted trigonal bipyramid.
同期刊论文项目
同项目期刊论文
The first 1D tetranuclear organotin(IV) complex with N '-acylsalicylhydrazide: Synthesis, characteri
Synthesis, characterization and crystal structure of a novel 3D network triorganotin(IV) polymer con
Synthesis, characterizations and crystal structures of new antimony (III) complexes with dithiocarba
Synthesis, spectroscopic and structural aspects of triphenylantimony(V) complex with internally func
Synthesis, characterization and crystal structure of binuclear diorganotin(IV) complexes derived fro
Synthesis, characterization and crystal structures of tri- and tetraphenylantimony(V) compounds cont
Synthesis, characterizations and crystal structures of antimony(III) complexes with nitrogen-contain
Octabutylbis{(E)-2-[4-(2-hydroxybenzylideneamino)phenyl]acetato}di-mu(2) -methoxo-di-mu(3)-oxido-tet
Octabutylbis{(E)-2-[4-(2-hydroxybenzylideneamino)phenyl] acetato}di-μ2-methoxo -di-μ3-oxido-tetratin
Synthesis, Characterization and Crystal Structure of a Trinuclear Diorganotin(IV) Complex with N?-ac
Cyclotrimeric and weakly-bridged cyclotetrameric organotin(IV) compounds assembled from 5-hydroxyiso
New organoantimony complexes with the isomers of chlorophenylacetic acid: Syntheses, characterizatio
Synthesis, Characterization, and Crystal Structure of Dinuclear Diorganotin(IV) Complexes Derived fr
期刊信息
位置：