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不同运动方式KDP单晶生长流动与物质输运数值分析
  • ISSN号:1005-023X
  • 期刊名称:《材料导报》
  • 时间:0
  • 分类:TB34[一般工业技术—材料科学与工程] O781[理学—晶体学]
  • 作者机构:[1]重庆大学动力工程学院,低品位能源利用技术及系统教育部重点实验室,重庆400030, [2]中电投远达环保工程有限公司重庆科技分公司,重庆401122
  • 相关基金:国家自然科学基金(51176208;51476014)
中文摘要:

针对两种不同运动方式下的KDP单晶生长,进行了流动与物质输运模拟。分析和比较了不同运动方式下,晶面附近溶液流动及晶面过饱和度分布特征。研究了晶体尺寸对晶面过饱和度场的影响。结果表明:二维运动法中,晶面遭受的水动力学条件较为复杂,使得其过饱和度分布不如转晶法规则;二维运动法锥面过饱和度明显高于转晶法;单位周期内,转晶法晶面平均过饱和度存在较大波动,而二维运动法过饱和度随时间变化较小;总体上看,小尺寸晶体时,二维运动法晶面过饱和度梯度小于转晶法;大尺寸晶体时,二维运动法晶面过饱和度梯度大于转晶法。

英文摘要:

Numerical simulations were conducted to model the flow and mass transfer involved in KDP crystals growth via two different motion modes. The features of solution flow around the crystal and the corresponding surface supersaturation distribution of two motion modes were compared and discussed. The effects of crystal size on surface supersaturation fields were analyzed. Simula- ted results indicated that when the 2D motion method (2D MM) was employed, the crystal surface experience complicate hydrody- namic conditions and its distribution of surface supersaturation was not as regular as that in rotating-crystal method. Additionally, its magnitude of pyramidal face was distinctly larger than that in rotating-crystal method. A considerable fluctuation occurred in surface supersaturation for a cycle in rotating-crystal method. By contrast, the variation of surface supersaturation in unit cycle was small as the crystal was grown by 2D MM. The gradient magnitude of surface supersaturation in 2D MM was less than that in rotating-crystal method for the smaller crystal, but it was larger than rotating-crystal method under the larger crystal.

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期刊信息
  • 《材料导报:纳米与新材料专辑》
  • 主管单位:重庆西南信息有限公司(原科技部西南信息中心)
  • 主办单位:重庆西南信息有限公司(原科技部西南信息中心)
  • 主编:
  • 地址:重庆市渝北区洪湖西路18号
  • 邮编:401121
  • 邮箱:matreved@163.com
  • 电话:023-67398525
  • 国际标准刊号:ISSN:1005-023X
  • 国内统一刊号:ISSN:50-1078/TB
  • 邮发代号:
  • 获奖情况:
  • 国内外数据库收录:
  • 被引量:3397