中文摘要：

以取代邻氨基苯甲酸为起始原料,经6步反应合成了7个多取代1,4-戊二烯-3-醇（7a～7g）;以7a～7g为原料,5 mol%Fe Cl3为催化剂,CH2Cl2为溶剂,于室温反应合成了7个螺环四氢喹啉衍生物（8a～8g）,其结构经^1H NMR,^13C NMR,IR和HR-MS（ESI）表征。采用X-射线单晶衍射研究了8d的晶体结构。结果表明：8d的晶胞参数a=14.001（3）A°,b=12.335（2）A°,c=11.587（3）A°,α=90°,β=95.497（2）°,γ=90°,V=1 991.9（7）A°^3,Z=4,μ=0.182 mm^-1,F（000）=816.0,R[F^2〉2σ（F^2）]=0.053 7,wR（F2）=0.132 5。

英文摘要：

Seven multi-substituted 1,4-pentadiene-3-ols（7a ～ 7g） were synthesized by a six-step reaction from substituted anthranilic acids. Seven spiro-tetrahydroquinoline compounds（8a ～ 8g） were synthesized from 7a -7g, using 5 mol% FeC13 as the catalyst and CH2Cl2 as solvent at rt. The structures were characterized by ^1H NMR, ^13C NMR, IR and HR-MS（ESI）. The crystal structure of 8d was investigated by X-ray single crystal diffraction. The results indicated that the crystal parameters of 8d were a =14.001（3）A°, b =12.335（2） A°, c=11.587（3）A°, α =90°, β=95.497（2）°, Y =90°, V=1 991.9（7）A°^3, Z=4,μ=0. 182 mm^-1, F（000） =816.0, R[F^2〉2σ（F^2）] =0.053 7, wR （F^2） =0. 132 5.