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表面等离激元对氮化硅薄膜中Tb^3+离子荧光寿命的影响
  • ISSN号:1000-7032
  • 期刊名称:《发光学报》
  • 时间:0
  • 分类:O482.31[理学—固体物理;理学—物理] O614.341[理学—无机化学;理学—化学]
  • 作者机构:[1]浙江大学硅材料国家重点实验室材料科学与工程系,浙江杭州310027
  • 相关基金:国家自然科学基金(60606001);国家重点基础研究发展计划(2007CB613403)资助项目
中文摘要:

利用等离子增强化学气相沉积和离子注入方法,制备了铽掺杂的氮化硅薄膜,然后利用磁控溅射和热处理工艺在薄膜上沉积了不同颗粒尺寸的银薄膜来研究表面等离激元共振对铽离子荧光寿命的影响。实验结果表明氮化硅中Tb^3+离子的光致荧光最强峰在547 nm,而银薄膜的存在会明显降低稀土离子Tb^3+的荧光寿命,其寿命的改变是由于银薄膜的表面等离激元改变了电磁场的分布,从而影响了系统的局域光模密度(PMD),理论计算的结果也验证了这一点。

英文摘要:

The motivation for developing silicon-based light emitters is the requirement of tiny light sources in the visible regions, which can be directly integrated into silicon chips for the analysis of different biological substances, for silicon optical couplers, and high-resolution low-cost micro displays. It is believed that the development of integrate circuit will open a door for the continuous increasing of silicon-based light emitters predicted by Moore's law. Many efforts, such as bulk silicon, Si nanocrystals, and rare earth (RE) coupled Si nanocrystals have been extensively studied. Weighing the studies mentioned above, rare RE-doped silicon light emitter, which has intense light emission even at room temperature, is a better candidate. In this report, the photoluminescence of Tb implanted SiNx films grown by plasma-enhanced chemical vapor deposition (PECVD) was investigated. And the effects of surface plasmon on the photoluminescence emission decay time of Tb^3+ doped SiNx films with different sized of Ag islands films were investigated. The photoluminescence (PL) and time resolved photoluminescence(TRPL)at room temperature show that the PL of SiNx: Tb3. film has the highest intensity at 547 nm with corresponding emission decay time 708 ms. After sputtering silver films, the TRPL of Tb^3+ ions shows the decrease of the emission decay time. An increase of emission decay time was observed due to the increased size of Ag islands after rapid thermal processing (RTP). We find good agreement between our experimental results and those predicted by a classical theory., which assumes the emitter to be a damped oscillating electric dipole. Therefore, it allows one to be confident that the silver islands do altered the emission decay time which correspondingly improve the internal quantum efficiency of the SiNx : Tb3

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期刊信息
  • 《发光学报》
  • 中国科技核心期刊
  • 主管单位:中国科学院
  • 主办单位:中国物理学会发光分会 中国科学院长春光学精密机械与物理研究所
  • 主编:申德振
  • 地址:长春市东南湖大路3888号
  • 邮编:130033
  • 邮箱:fgxbt@126.com
  • 电话:0431-86176862
  • 国际标准刊号:ISSN:1000-7032
  • 国内统一刊号:ISSN:22-1116/O4
  • 邮发代号:12-312
  • 获奖情况:
  • 物理学类核心期刊,2000年获中国科学院优秀期刊二等奖,中国期刊方阵“双效”期刊
  • 国内外数据库收录:
  • 美国化学文摘(网络版),荷兰文摘与引文数据库,美国工程索引,美国剑桥科学文摘,日本日本科学技术振兴机构数据库,中国中国科技核心期刊,中国北大核心期刊(2004版),中国北大核心期刊(2008版),中国北大核心期刊(2011版),中国北大核心期刊(2014版),中国北大核心期刊(2000版)
  • 被引量:7320