采用直接沉淀法制备PbWO_4有序纳米结构,以草酸根双羧基阴离子为其生长阶段结构导向剂。使用X射线粉末衍射(XRD)、扫描电子显微镜(SEM)、红外光谱(IR)和透射电子显微镜(TEM)等手段对其表征,研究了草酸根离子在PbWO_4纳米晶生长阶段的控制作用,并提出了PbWO_4有序纳米结构的形成机理.
Ordered PbWO_4 nanostructures were synthesized by a direct precipitation method,and the oxalate anions with double carboxyl were employed as structure-directing agents in the growth stage of PbWO_4 nanocrystals.The PbWO_4 nanostructures were characterized by X-ray power diffraction(XRD), scanning electron microscopy(SEM),infra-red spectrum(IR) and transmission electron microscopy(TEM). The control role of the oxalate anions in the growth stage of PbWO_4 nanocrystals was investigated and formation mechanism of the ordered PDWO_4 nanocrystals was proposed.