采用蒸发诱导自组装法制备了高度有序的TiO2介孔薄膜.利用x射线衍射(XRD)、扫描电子显微镜(SEM)和透射电子显微镜(TEM)等分析手段对其进行了表征.结果表明,所得样品的孔径约为5nm,孔道规则,且骨架为纯锐钛矿结构.紫外-可见光谱(uV—Vis)的表征结果表明,制备的TiO2介孔薄膜对波长小于380nm的紫外线有很强的吸收.对TiO2介孔薄膜的I-V(电流-电压)特性进行了表征,发现加光后其I-V曲线由暗态时的肖特基特性转变为欧姆特性,表明TiO2介孔薄膜对紫外光有很敏感的光电响应.
Highly orderded TiO2 mesoporous thin films were synthesized through evaporation induced self- assembly(EISA). The as-synthesized samples were characterized by X-ray diffraction (XRD), scanning elec- tron microscope(SEM), and transmission electron microscope(TEM). The results show that the mesoporous sample has a highly organized and nanocrystaline anatase framework with pore size of about 5 nm. The UV-Vis spectra reveal that TiO2 mesoporous thin films have strong absorbance to UV light(A 〈380 nm). The I-V(cur- rent-voltage) properties of TiO2 mesopomus thin films were characterized. The results show that the I-V characteristics have changed when UV light is on and off, which indicate that TiO2 mesoporous thin films have sensitive ultraviolet photoelectric response.