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基于形态学分析红枫湖沉积物中重金属的分布特征及污染评价
  • ISSN号:0254-6108
  • 期刊名称:环境化学
  • 时间:0
  • 页码:440-446
  • 分类:X53[环境科学与工程—环境工程]
  • 作者机构:[1]贵州师范大学贵州省山地环境信息系统与生态环境保护重点实验室,贵阳 550001
  • 相关基金:国家自然科学基金项目(No.20967003).
  • 相关项目:高原喀斯特地区深水湖泊重金属迁移转化规律与治理方案探讨
中文摘要:

采用Tessier连续浸提法对红枫湖沉积物中Cd、Pb、Cu、Cr、Zn、Ni、Fe、Mn 8种重金属元素进行化学形态分析.应用次生相与原生相比值法(RSP)和次生相富集系数法(SPEF)对沉积物中重金属元素的人为污染进行评价,分析不同评价方法对结果的影响.结果表明:该湖泊沉积物中Mn主要以铁锰氧化物结合态存在,Cd主要以可交换态存在,元素Pb、Cu、Cr、Zn、Ni、Fe则主要以残渣态存在.RSP法适用范围较小,且缺乏客观性,故本研究主要依据SPEF法对红枫湖沉积物的重金属污染进行评价.Cu的平均KSPEF值高达22.7,明显受到了人为污染;Zn、Ni、Fe、Cr(KSPEF〉1)都具有一定的潜在生态危害;靠近工业区的北湖湖区沉积物中重金属污染程度明显高于南湖.

英文摘要:

The chemical speciation of eight heavy metals (Cd, Pb, Cu, Cr, Zn, Ni, Fe and Mn) in sediments from Hongfeng Lake, the largest man made lake on the Guizhou Plateau, was studied based on the Tessier sequential fractionation. Both the ratio of secondary phase to primary phase (RSP) and secondary phase enrichment factor (SPEF) were employed to assess heavy metal pollution in sediments, and the outcome of these two assessment methods was compared and analyzed. The results obtained in this study are as follow: Mn and Cd in the sediments existed primarily in the Fe and Mn oxide-bound fraction and in exchangeable fraction respectively, while Pb, Cu, Cr, Zn, Ni and Fe were mainly distributed in residue phase. Since the RSP method has a limited scope of applicability, the present assessment is based principally on the SPEF approach. By using the SPEF method, it was revealed that the average KSPEF of Cu was up to 22.7. As a conclusion, the lake was obviously polluted by anthropogenic sources ; Zn, Ni, Fe and Cr (KSPEF 〉 1 ) had a certain degree of potential ecological risks; Heavy metal pollution in the north area of the lake, which is adjacent to the industrial zone, was clearly more severe than that in the south area.

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期刊信息
  • 《环境化学》
  • 北大核心期刊(2011版)
  • 主管单位:中国科学院
  • 主办单位:中国科学院生态环境研究中心
  • 主编:郭良宏
  • 地址:北京2871信箱
  • 邮编:100085
  • 邮箱:hjhx@rcees.ac.cn
  • 电话:010-62923569
  • 国际标准刊号:ISSN:0254-6108
  • 国内统一刊号:ISSN:11-1844/X
  • 邮发代号:82-394
  • 获奖情况:
  • 国内外数据库收录:
  • 俄罗斯文摘杂志,美国化学文摘(网络版),美国剑桥科学文摘,日本日本科学技术振兴机构数据库,中国中国科技核心期刊,中国北大核心期刊(2004版),中国北大核心期刊(2008版),中国北大核心期刊(2011版),中国北大核心期刊(2014版),英国英国皇家化学学会文摘,中国北大核心期刊(2000版)
  • 被引量:27127