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高密度聚乙烯和硬脂酸对石蜡基粘结剂流变行为的影响
  • 期刊名称:机械工程材料
  • 时间:0
  • 分类:TF124.39[冶金工程—粉末冶金;冶金工程—冶金物理化学]
  • 作者机构:[1]湖南大学材料科学与工程学院,长沙410082, [2]克鲁日科技大学,克鲁日-纳波卡3400,罗马尼亚
  • 相关基金:国家自然科学基金资助项目(50674044);中国博士后科学基金资助项目;国家留学基金资助项目;湖南省自然科学基金资助项目(05JJ30199)
  • 相关项目:热氢处理与钛粉末注射成形的复合及其机理研究
中文摘要:

使用旋转式流变仪研究了加入质量分数10%~30%的高密度聚乙烯和0~9%的硬脂酸后石蜡基粘结剂在120~162℃的流变行为。结果表明:粘结剂中石蜡与高密度聚乙烯含量之比K值对其黏度有重要影响,K值越小,黏度越大;当K≥4时,提高温度和加入硬脂酸不能降低其黏度;当K〈4时,提高温度是改善粘结剂流变性能的有效手段之一,而硬脂酸加入量存在一个临界值,只有超过该值时才能有效降低黏度;随K值减小,硬脂酸临界加入量也逐步降低;粘结剂熔体在150℃下表现出类似牛顿流体的流变行为。

英文摘要:

The rheological behaviors of wax-based binders with high density polyethylene content from 10wt% to 30wt% and stearic acid (SA) content from 0 to 9wt% were studied by using rotary rhemeter in the temperature range of 120 to 162℃. The results show that the ratio of wax content to high density polyethylene content in binder, named as K, put a heavy impact on viscosity and the higher the K was, the lower the viscosity was. For a binder with K more than 4 raising temperature and adding SA showed little effect on reducing its viscosity, but raising temperature sounded an important and effective measure for those with K less than 4. Adding SA could reduce the viscosity, when its addition was over a threshold value. The threshold addition of SA decreased gradually with K decrease. The binder melt at 150 ℃ showed such rheological behaviors like a Newtonian viscous fluid.

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