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含碳球团还原熔分综合利用硼铁精矿新工艺
  • ISSN号:0253-6099
  • 期刊名称:《矿冶工程》
  • 时间:0
  • 分类:TF556[冶金工程—钢铁冶金]
  • 作者机构:[1]北京科技大学钢铁冶金新技术国家重点实验室,北京100083
  • 相关基金:国家自然科学基金资助项目(51274033)
中文摘要:

基于硼铁矿资源综合利用的现状和转底炉珠铁工艺的基本特点,提出了含碳球团还原熔分综合利用硼铁精矿的新工艺。在实验室条件下,以硼铁精矿和碳质还原剂为原料,系统研究了焙烧温度、配碳量(C/O摩尔比)、还原剂种类、熔融保持时间等因素对球团还原熔分过程的影响,以及熔分产物的基本特眭。试验结果表明:焙烧温度过高或过低均不利于熔分;提高配碳量有助于缩短还原熔分时间;煤灰熔点对熔分有较大影响;随着熔融保持时间的延长渣中FeO含量降低。优化的工艺参数为:以无烟煤为还原剂,配人量为C/O=1.2,焙烧温度为1400℃,焙烧时间为15min。此时,渣铁分离彻底,得到含硼元素0.065%的纯净珠铁和B203品位为20.01%的富硼渣,珠铁中铁的收得率在96.5%以上,富硼渣中硼的收得率在95.7%以上。经缓冷处理,富硼渣主要由遂安石和橄榄石两相组成,活性达86.46%。含硼珠铁和富硼渣分别是钢铁和硼化工工业的优质原料,该工艺可为我国低品位硼铁矿的综合利用提供一种新思路。

英文摘要:

According to the current situation of paigeite utilization and basic characteristics of iron nugget production in rotary hearth furnace (RI-IF), a novel technology was proposed for comprehensive utilization of boron-bearing iron concentrate by reduction and melting-separation of carbon-containing pellet. In the lab test, with boron-bearing iron concentrate and carbonaceous reducing agent as raw material, effects of those factors including temperature, carbon content( C/O mole ratio), reducing agents and duration of melting process on processes of reduction and melting- separation for the pellet, as well as properties of products from melting-separation were all thoroughly investigated. Test results show that both too high and too low temperature were not favorable to the melting-separation process, while increasing carbon content could help shortening reduction and melting-separation time. Ash fusion point can bring a big difference on the melting-separation effect. The FeO content in the slag decreased with the duration of melting-separation process being prolonged. Under the following optimal conditions, that is, by using anthracite as reducing agent with C/O of 1.2, iron could be completely separated from slag after 15 mins of reduction at a reduction temperature of 1 400 ~C, yielding a nugget containing 0.065% boron with iron recovery over 96.5%, and the boron-rich slag grading 20.01% boron oxide with boron recovery over 95.7%. After slow-cooling process, boron-rich slag was mainly composed of suanite and olivine, with efficiency of boron extraction up to 86.46%. Both boron-bearing nugget and boron-rich slag are good raw materials for metallurgy and boron industry. This new technology can provide reference for comprehensive utilization of low grade paigeite in China.

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期刊信息
  • 《矿冶工程》
  • 北大核心期刊(2011版)
  • 主管单位:长沙矿冶研究院有限公司
  • 主办单位:长沙矿冶研究院有限公司 中国金属学会
  • 主编:曾维勇
  • 地址:湖南省长沙市麓山南路966号
  • 邮编:410012
  • 邮箱:kygc@2118.cn kuangyegongchengzz@163.com
  • 电话:0731-88657176 8657070 88657173
  • 国际标准刊号:ISSN:0253-6099
  • 国内统一刊号:ISSN:43-1104/TD
  • 邮发代号:42-58
  • 获奖情况:
  • 中国期刊方阵“双效”期刊
  • 国内外数据库收录:
  • 美国化学文摘(网络版),荷兰文摘与引文数据库,美国剑桥科学文摘,日本日本科学技术振兴机构数据库,中国中国科技核心期刊,中国北大核心期刊(2004版),中国北大核心期刊(2008版),中国北大核心期刊(2011版),中国北大核心期刊(2014版),中国北大核心期刊(2000版)
  • 被引量:11358