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立方氮化硅的冲击波合成实验研究
  • 期刊名称:无机材料学报,2007,22(1):159~162
  • 时间:0
  • 分类:O771[理学—晶体学] TB383[一般工业技术—材料科学与工程]
  • 作者机构:[1]中国工程物理研究院流体物理研究所冲击波物理与爆轰物理实验室,绵阳621900, [2]西南科技大学材料科学与工程学院,绵阳621010
  • 相关基金:国家自然科学基金(50472102);中国工程物理研究院科学技术基金(20050864)
  • 相关项目:立方氮化硅的合成及烧结研究
中文摘要:

以α-Si3N4粉体作原材料,采用炸药爆轰平面飞片加载装置和样品回收技术进行了冲击波合成实验,完整回收到合成样品,经过酸处理,对回收样品进行X射线衍射分析,结果表明:当加载压力超过50GPa而且冲击温度约3600-5000K时,α-Si3N4可以较完全地转化为γ-Si3N4.本实验的研究结果建立了一种冲击压缩技术可单次合成克量级的立方氮化硅,为进一步开展立方氮化硅的性能研究奠定了基础.

英文摘要:

Experiments using a planar metal disc flyer driven by explosives and a cylindrical chamber was designed to synthesize cubic silicon nitride with the mixtures of α-Si3N4 and copper powders as starting materials. Shock-compressed samples were successfully recovered. The recovered samples were nitrated to resolve copper, and the separated silicon nitride powders were analyzed by XRD. The results indicate that most of α-Si3N4 are transformed into cubic silicon nitride when a shock pressure larger than 50GPa and a matched shock temperature simultaneously load on α-Si3N4. The experiments provide a shock compression technique that can synthesize cubic silicon nitride in the order of gram mass in one test run, which lay the foundation for conducting further investigation on the properties and performance of cubic silicon nitride.

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