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中文摘要：
通过共轭聚合物侧链接枝或末端基引发聚合非对称单甲基丙烯酸锌酯，弱碱水解原位制备有机共轭聚合物/ZnO纳米晶杂化薄膜；共聚物溶液电纺丝，原位水解制备有机共轭聚合物/ZnO纳米晶杂化纳米纤维。研究共轭聚合物与纳米晶电子相互作用，研究杂化体系量子效应。由于原位形成的聚合物与无机纳米晶之间的键接作用，可以有效抑制杂化体系的相分离，同时聚合物能原位控制纳米晶的生长，形成适当的微相分离，表面聚合物进一步改善纳米晶量子点表面空穴位，提高杂化体系光学稳定性。
英文摘要：
nanocrystals；self-assembly；in situ growth；nanocomposites；
结论摘要：
通过杂化嵌段聚噻吩原位水解或分解，形成共轭聚合物/纳米晶杂化异质结，调控纳米晶的形貌，形成纳米粒子组装成的纳米棒，实现有效杂化异质结界面。提出了液晶取向诱导纳米晶自组装、嵌段自组装原位生长界面调控以及嵌段自组装原位界面诱导和界面原位加工改性调控纳米复合活性层微观形貌和活性层与电极界面相容性以及载流子传输势垒，实现了给/受体纳米复合体系有序性构筑，改善了给受体界面和各层界面相互作用，缩小了载流子传输势垒，提高了器件短路电流，取向界面功函。该项目已在国际权威刊物如Chem. Mater. (8.238); Macromolecules (IF: 5.521); J. Mater. Chem. (IF: 6.101); J. Phys. Chem. C (IF: 4.814); ACS Appl. Mater. Interfaces (IF: 5.008); Polym. Chem. (IF: 5.231)等国际权威刊物上相继发表论文近36篇，其中影响因子大于3 以上29余篇。作为第1完成人获省自然科学二等奖2项。
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期刊论文
Approach to cross-linked polynorbornene/ZnO nanocomposites through nitroxide-mediated free radical g
Controlling morphology and improving the photovoltaic performances of P3HT/ZnO hybrid solar cells vi
In situ growth nanocomposites composed of rodlike ZnO nanocrystals arranged by nanoparticles in a se
Photovoltaic performance enhancement in P3HT/ZnO hybrid bulk-heterojunction solar cells induced by s
Hybrid bulk heterojunction solar cells based on poly(3-hexylthiophene) and ZnO nanoparticles modifie
Efficiency and Air-Stability Improvement of Flexible Inverted Polymer Solar Cells Using ZnO/Poly(eth
Hybrid Bulk Heterojunction Solar Cells Based on the Cooperative Interaction of Liquid Crystals withi
Enhancement of the ultraviolet emission of ZnO nanorods by terphenyl liquid-crystalline ligands modi
Synthesis of transparent ZnO/PMMA nanocomposite films through free-radical copolymerization of asymm
Influence of water-soluble polythiophene as an interfacial layer on the P3HT/PCBM bulk heterojunctio
A Novel Planar D-A Alternating Copolymer with D-A Integrated Structures Exhibiting H-Aggregate Behav
Donor-Acceptor Integrated Conjugated Polymers based on Carbazole[3,4-c:5,6-c]bis[1,2,5]thiadiazole w
High Efficiency of Poly(3-hexylthiophene)/[6,6]-phenyl C-61 Butyric Acid Methyl Ester Bulk Heterojun
Photocrosslinkable liquid-crystalline polymers for stable photovoltaics by adjusting side-chains spa
Observations of energy transfer and anisotropic behavior in ZnO nanoparticles surface-modified by li
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