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中文摘要：
氢气作为高燃烧热和无污染的理想能源日益受到各国的普遍关注和高度重视。利用氢能的关键是氢的规模储藏和运输。因此储氢材料成为材料学研究的热点。微孔金属-有机框架聚合物由于孔洞大小和体积可调控、比表面积大而引起人们的极大兴趣。由于多孔配位聚合物作为储氢材料的研究在国际上刚刚兴起，我国在该领域的研究还处于起步阶段，因此，本课题期望通过羧基取代磺酰化氨基酸类化合物等作为主配体，用多酸类和含氮类化合物作为第二配体与过渡金属或轻金属反应，在温和条件下制备多孔配位聚合物，并研究其对氢气的吸附作用。采取多种优化结构和优化孔洞的的实验手段，提高氢气和其它气体的吸附量，从而设计、开发新的储氢材料和其它气体吸附材料，并尝试探索吸附作用的内在机理,为利用氢能开辟新的途径。
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期刊论文
An anion-directed unprecedent three–dimensional array with erbium(III) based on the 2,6–pyridinedica
Series of anion-directed lanthanide-rigid-flexible frameworks: syntheses, structures, luminescence a
Self-assembly and Magnetic Characterization of Two CuII Complexes Constructed by 2,2'-Bipyridine and
An End-to-end Dicyanamido-bridged Heteronuclear Cu(II)/Na(I) Coordination Polymers: Synthesis, Elect
Unprecedetent 4-and 6-Connected 2D Coordination Networks Based on 4,4-Subnet Tectons, Showing Unusua
Self-Assembly of a Series of Cobalt(II) Coordination Polymers Constructed from H2tbip and Bipyridine
A series of lanthanide–organic polymers incorporating nitrogen-heterocyclic and aliphatic carboxylat
Syntheses, Structures, and Photoluminescence of a Series of d10 Coordination Polymers with R-Isophth
Synthesis, Crystal Structure and Magnetic Properties of an Oxalato-bridged Dinickel(II) Complex with
Novel Flexible Multidentate Ligands for Crystal Engineering: Syntheses, Structures and Properties of
Syntheses, Structures and Luminescent Properties of Two Zinc Complexes Containing N-P-Acetamidobenze
A Dicyanamido-bridged Zinc(II) Complex Based on the Bis(4-pyridyl)ethane with
a Three-dimensional Fr
Hydrothermal Syntheses and Characterizations of Three ZnII Coordination Polymers Tuned by pH Value a
Synthesis, Crystal Structures and Magnetic Properties of Copper(II) Complexes
with Nitronyl Nitroxid
Hydrothermal Synthesis and Properties of a New 3D Lanthanum Supramolecule Based on the 4-Hydroxypyri
Syntheses and Structures of Three Cobalt Metal-organic Frameworks with 3-(Sulfonyl-glycine)benzoic A
Various coordination architectures constructed from N-[(carboxyphenyl) -sulfonyl]glycine: Structural
Crystal Structure and Electrochemistry Properties of an Iron(III) Complex Based on the 3,5-Pyridined
A New One-dimensional Dicyanamide Bridged Zinc(II) Complex Containing Nitronyl Nitroxide Radicals: S
Copper(II) 5-methoxyi sophthalate coordination polymers incorporating dipyridyl co-ligands: synthese
Chain, Pillar, Layer, and Different Pores: A -[(3-Carboxyphenyl) sulfonyl]glycine Ligand as a Versat
Synthesis, crystal structures and magnetic properties of a new radical NIT-10-MeBzIm and the corresp
Pyrazole-Nitrogen Bridged Tetranuclear Copper(II) Cluster with An Unprecedented U-like Core: Synthes
A novel Potassium Complex Based on the Taurine-Salicylaldehyde Schiff Base, Synthesis, Crystal Struc
A series of lanthanide-rigid-flexible frameworks Based on 2-Propyl-1H-imidazole-4,5-dicarboxylate an
Structural Variation from 1D to 3D: Effects of Temperature and pH Value on the Construction of Co(II
Delicate substituent effect of isophthalate tectons on the structural assembly of diverse 4-connecte
A novel 3D Mn(II) coordination polymer involving 4,4-dipyridylsulfide and 4,4-dipyridyltrisulfide ob
Synthesis and crystal structures of ternary copper(II) complex containing salicylaldehyde Schiff bas
A Novel Complex of Na(I)-Nitronyl Nitroxide [Na(NIT-1?-MeBzIm)3]ClO4: Synthesis and Crystal Structur
Hydrothermal preparation, crystal structures and properties of novel Mn(II) metal–organic frameworks
Structures and Thermal Properties of a cobalt Complexes Containing N- 4Carboxyphenyl Sulfonyl Ligand
Synthesis and Crystal Structure of a Two-dimensional Cobalt Complex with 5-Tert-butyl Isophthalic Ac
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