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中文摘要：
本项目拟从CO2 气体与氨基、羟基以及富电子的含氮芳环具有特殊的亲和作用出发，设计合成一系列含有这些功能基团的配体进而合成具有特殊功能的微孔MOFs，将氨基、羟基以及富电子的含氮芳环引入到MOFs孔道表面，以期对CO2 产生选择性吸附，并提高对CO2的吸附量。通过研究吸附条件、吸附机理，筛选出吸附量大、选择性好的MOFs CO2 吸附材料，为CO2的分离和捕集提供理论依据和应用借鉴。
英文摘要：
Carbon Dioxide Capture；Metal-Organic framework；Synthesis;；Capture Mechanism；Structure and property
结论摘要：
本项目按照计划书的设想，结合该领域的研究进展，从CO2 气体与氨基、羟基以及富电子的含氮杂环具有特殊的亲和作用出发，设计合成了一系列含有这些功能基团的有机配体，进而合成具有特殊功能的单核、双核、及多维的微孔MOFs。将氨基、羟基、甲基以及富电子的含氮芳环羟基与共轭芳环结合，通过设计合成含有这些功能基团的配体，将这一系列配体和轻过渡金属、后过渡金属或者碱金属、轻稀土金属进行组装，设计合成孔道表面具有氨基、羟基以及富电子的含氮芳环等多孔配位聚合物，引入到MOFs 孔道表面，以期对CO2 产生选择性吸附，并提高对CO2 的吸附量。通过研究吸附条件、吸附结果，探讨吸附机理，筛选出吸附量大、选择性好的MOFs CO2 吸附材料，为CO2 的分离和捕集提供理论依据和应用借鉴。对项目实施过程中遇到一些实际问题，正在一一去探索解决。
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期刊论文
Synthesis, Crystal Structure and Magnetic Properties of a Novel Azide-bridged Copper(II) Coordinatio
Ancillary ligand-mediated syntheses and fluorescence properties of zinc(II) complexes based on flexi
A EuriumOrganic Polymer Incorporating 1-H, 2-Ethyl-4,5-Imidazole Dicarboxylate, and Formate Ancillar
Synthesis, Crystal Structure, and Luminescence Property of a New Zinc(II) Complex With Schiff-Base C
Two unique lanthanide-organic frameworks based on 1H-2-methyl-4,5-imidazole-dicarboxylate and oxalat
Hydrothermal Synthesis, Crystal Structure and Characterization of a 1D Neodymium(III) Coordination P
Co-II and Zn-II Coordination Frameworks with Benzene-1,2,3-tricarboxylate Tecton and Flexible Dipyri
Tetrahedral/octahedral frameworks with different local interruptions: Syntheses and structures of tw
New coordination polymers from 1D chain, 2D layer to 3D framework constructed from 1,2-phenylenediac
A comparison of the coordination preference of Cd, Zn, Cu(II) with flexible homophthalic acid and ri
Five M(II) coordination polymers assembled from various polynuclear units spaced by semirigid carbox
Syntheses, structures and photoluminescence of five zinc(II) coordination polymers based on 5-methox
Syntheses, structures and properties of two manganese(II) metal-organic frameworks based on bromoiso
A novel two-dimensional 3d-4f heterometallic coordination polymer with (4,4)-connected topology: Cry
Synthesis, Structure, and Characterization of an Organic Compound Based on 3-Nitrobenzoic Acid Moiet
Divalent metal coordination polymers assembled from dual linkers - semirigid carboxyphenylpropionate
Three Zn(II) metal-organic frameworks assembled from a versatile tecton 5-ethyl-pyridine-2,3-dicarbo
Lanthanide coordination polymers based on multi-donor ligand containing pyridine and phthalate moiet
Two topologically new trinodal cobalt(II) metal-organic frameworks characterized as a 1D metallic ox
A ytterbium polymer incorporating ethyl-4,5-imidazole-dicarboxylate and formate coligand: Structure,
Two- and Three-Dimensional Divalent Metal Coordination Polymers Constructed from a New Tricarboxylat
Mn-II Coordination Polymers Based on Bi-, Tri-, and Tetranuclear and Polymeric Chain Building Units:
A Series of Heterometallic Three-Dimensional Frameworks Constructed from Imidazole-Dicarboxylate: St
Coligand-regulated assembly, fluorescence, and magnetic properties of Co(II) and Cd(II) complexes wi
Two new 3-D coordination polymers with 5-tert-butyl isophthalic acid and flexible N-donor co-ligands
Structural modulation and properties of four cadmium(II) coordination architectures based on 3-(pyri
Structural and fluorescent regulation of Cd(II) coordination polymers with homoterephthalate by N-do
A Cd(II) Coordination Polymer Containing 4-(1-H-imidazol-2-yl) Benzoic Acid Ligand: Synthesis, Cryst
A novel praseodymium coordination polymer with Pcu topology: Crystal structure, thermal decompositio
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