位置：立项数据库 > 立项详情页
高分子材料多层次结构及结构调控
  • 项目名称：高分子材料多层次结构及结构调控
  • 项目类别：创新研究群体科学基金
  • 批准号：50521302
  • 申请代码：E0309
  • 项目来源：国家自然科学基金
  • 研究期限：2006-01-01-2008-12-31
  • 项目负责人：黄勇
  • 负责人职称：研究员
  • 依托单位：中国科学院化学研究所
  • 批准年度：2005
中文摘要：

三年来，在能源新材料和生物医用高分子材料以及在水处理材料方面开展了研究。在大分子链结构的设计、制备和调控，聚集态结构的演变机制和调控，以及多重结构高分子复合材料的制备和性质三个层次的基础研究方面都取得了突破，并形成了若干具有自主知识产权的原创性系列成果。在过去三年中共发表论文142篇，其中在J. Am. Chem. Soc.、Angew. Chem. Int. Ed.、Adv. Mater.等影响因子大于6的学术期刊上发表论文12篇，在Macromolecules、J. Phys. Chem. B、Chem. Commun.、J. Polym. Sci. Part A: Polym. Chem.、Macromol. Rapid Commun等影响因子大于3的学术期刊上发表论文78篇。申请发明专利26项，其中6项发明专利获授权。特别是在能源新材料领域中，通过利用在基础研究中对聚丙烯多层次结晶结构及结构调控过程的深入认识，发展了基于聚丙烯薄膜的锂离子电池隔膜制备技术和工艺，建成了一条年产聚丙烯型锂离子电池隔膜600万平米的中试生产线，解决了中试及生产中的关键技术问题。

中文主题词：
成果综合统计
成果类型
数量
  • 期刊论文
  • 会议论文
  • 专利
  • 获奖
  • 著作
  • 160
  • 70
  • 0
  • 0
  • 5
期刊论文
纤维素基储能调温超细纤维的制备
Composition of the cell wall in the stem and leaf sheath of wheat straw
A novel, amphiphilic ethyl cellulose grafting copolymer with poly(2-hydroxyethyl methacrylate) side
Conjugated polymers containing electron-transporting, hole-transporting, and light-emitting units in
Synthesis of Cu-In-S Ternary Nanocrystals with Tunable Structure and Composition
Surface biofunctionalization of biodegradable polymer microcarriers for cell growth
Synthesis of porphyrin-embedded dendronized polymers by suzuki polycondensation
第30次双清论坛，软物质材料科学前沿与交叉问题研讨会
Japan-China Joint Symposium on Functional Supramolecular Architectures
Stereocomplexation and Monolayer Morphologies of a Stereoregular Poly(methylmethacrylate) Mixture Fo
The orientation and photophysical properties of conjugated polymers in oriented films
The morphology and photoelectronic properties of poly(9,9’-dioctylfluorene)/ethyl-cyanoethyl cellu
A study on the double melting behavior of poly(trimethylene terephthalate)
Electrospun hydroxypropyl methyl cellulose phthalate (HPMCP)/erythromycin fibers for targeted releas
Studies of green emission in polyfluorenes using a model polymer
Crystallization behavior of a propylene-1-butene random copolymer in its α and γ modifications
The influence of pH on a hydrogen-bonded assembly film
超疏水表面的研究进展研究
R and a Interfacial Structures of the iPP/PET Matrix/Fiber Systems
Water uptake behavior of hydrogen-bonded PVPON–PAA LBL film
Fabrication and characterization of an organic-inorganic gradient surface made by polymethylsilsesqu
超声化学在降解水中有机污染物的应用
The effect of substrate on the annealing of poly(butylene succinate) single crystals
Multiple melting behavior of poly(butylene succinate
A morphological study of poly(butylene succinate)/poly(butylene adipate) blends with different blend
纳米粒子尺寸效应引起的内层电子结合能位移
A simple approach for fabricating a superhydrophobic surface based on poly(methyl methacrylate)
Synthesis and photocurrent response of porphyrin-containing conjugated polymers
Melt crystallization and crystal transition of poly(butylene adipate) revealed by infrared spectrosc
Synthesis and self-assembly of amphiphilic dendronized conjugated polymers
Enhancement of two-photon absorption cross-section and singlet-oxygen generation in porphyrin-cored
Hierarchical supramolecular self- assembly of nanotubes and layered sheets
Spiro-bridged ladder-type poly(p-phenylene)s: towards structurally perfect light-emitting materials
Clathrate (δ) form crystal transitions of syndiotactic polystyrene in atactic polystyrene networks
Flexible bi-continuous mesostructured inorganic/ polymer composite membranes
Effect of crystallization temperature and propylene sequence length on the crystalline structure of
A comprison study on the melt crystallization kinetics of long chain branched and linear isotactic p
Synthesis and phase transition of cellulose- graft-poly(ethylene glycol) copolymers
Simultaneous tuning of chemical composition and topographyof copolymer surfaces: micelles as buildin
AFM study of crystallization and melting of a poly(ethylene oxide) diblock copolymer containing a ta
Tris[tri(2-thienyl)phosphine]palladium as the catalyst precursor for thiophene-based Suzuki-Miyaura
Functional mesoporous polymers from phenolic building oligomers
Effects of Chain Conformation and Entanglement on the Electrospinning of Pure Alginate
高压静电场纺丝法制备羟丙基甲基纤维素邻苯二甲酸酯超细纤维
Quasi-one-dimensional arrangement of silver nanoparticles templated by cellulose microfibrils
Initial Stage of iPP β to α Growth Transition Induced by Stepwise Crystallization
Electrically induced linear locomotion of polymer gel in air
In-situ Investigation of Molecular Diffusion in Hydrogels
The influence of crystal structures of nucleating agents on the crystallization behaviors of isotact
Synthesis and characterizations of graft copolymer of ethylcellulose with poly(caprolactone monoacry
Porous carbon and carbon composite hollow spheres
The crystallization morphology and melting behavior of polymer crystals in nano-sized domains
电场纺丝法制备药物缓释乙基纤维素纤维的研究
Janus colloids formed by biphasic grafting at a pickering emulsion interface
Template synthesis of hydrogel composite hollow spheres against polymeric hollow latex
Porous hollow carbon nanotube composite cages
Synthesis of amphiphilic ethyl cellulose grafting poly(acrylic acid) copolymers and their self-assem
Rod-like crystal growth of dioctyl substituted polyfluorene from nematic and isotropic states
Photoinduced graft copolymerization of polymer surfactants based on hydroxyethyl cellulose,
A supramolecular chiroptical switch based on chitosan and anionic porphyrin complex film
A stable and high-efficiency blue-light emitting terphenyl-bridged ladder polysiloxanes
Confined Synthesis of a cis-Isotactic Ladder Polysilsesquioxane by Using a p-Stacking and H-Bonding
Morphology and crystalline structure of poly(ε-caprolactone) nanofiber via porous aluminium oxide te
General synthesis of hollow composite ellipsoids
2nd International Symposium on Electron Microscopy of Polymer Systems
Responsive periodic mesoporous polydiacetylene/ silica nanocomposites
Mesoporous carbon/silica nanocomposite through multi-component assembly
Aerosol assisted synthesis of silica/phenolic resin composite mesoporous hollow spheres
Structure characterization of melt drawn polyethylene ultrathin films
Template synthesis of composite hollow spheres using sulfonated polystyrene hollow spheres
Study of the morphology of poly(butylene succinate)/poly(ethylene oxide) blends using hot-stage atom
超分子构筑调控合成结构规整的梯形聚合物及其应用研究
A novel shape-stabilized PCM: Electrospun ultrafine fibers based on lauric acid/polyethylene terepht
Morphology and permeability of cellulose/chitin blend membranes
Surface-induced anisotropic chain ordering of polycarprolactone on oriented polyethylene substrate:
Biologically inspired path-controlled linear locomotion of polymer gel in air
Filed drive gel actuator with versatile long-range locomotion in air
A unique behavior of water drops induced by low-density polyethylene surface with a sharp wettabilit
From cloudy to transparent: chain rearrangement in hydrogen-bonded layer-by-layer assembled films
Fabry–Pérot fringes of hydrogen-bonded assembly films
Template synthesis of hierarchically structured composites
Random lasing in a dye doped cholesteric liquid crystal polymer solution
Self-assembly of ethyl cellulose-graft- polystyrene copolymers in acetone
Protein diffusion in agarose hydrogel in situ measured by improved refractive index method
Epitaxial crystallization of poly(butylene adipate) on highly oriented isotactic polypropylene thin
第309次香山科学会议：软物质科学的最新进展与发展趋势
335次香山科学会议：高性能聚丙烯腈碳纤维制备的基础科学问题
A general approach toward opal–inverse opal interlocked materials
Low-temperature facile template synthesis ofcrystalline inorganic composite hollow spheres
Templated synthesis of composite rings using core-shell toroids
Template synthesis of tin-doped indium oxide (ITO)/polymer and the corresponding carbon composite ho
The EB-DNA liquid crystalline complex with high concentration of Mg2t
Covalent functionalization of multi-walled carbon nanotube surfaces by conjugated polyfluorenes
Synthesis and characterization of star polyfluorenes with a C60 core
Controllable Distribution of Single Molecules and Peptides within Oligomer Template Investigated by
Photophysical and Electroluminescent Properties of Hyperbranched Polyfluorenes
Synthesis, self-assembly, and thermosensitive properties of ethyl cellulose-g-P(PEGMA) amphiphilic c
A simple and efficient route to prepare inorganic compound/polymer composites in supercritical fluid
China-Netherlands Bilateral Symposium on Electron Microscopy of Polymer Systems
Reversible thermally responsive and luminescent coil–rod–coil triblock copolymers
Synthesis of monodisperse spiro-bridged ladder-type oligo-p-phenylenes
A Raman-Scattering Study on the Net Orientation of Biomacromolecules in the out Epidermal Walls of M
Porphyrin-Cored Star Polymers as Efficient Nondoped Red Light-Emitting Materials
Crystal orientation in poly(ethylene 2,6- naphthalate) ultrathin films revealed by reflection- absor
Effect of fiber molecular weight on the interfacial morphology of iPP fiber/matrix single polymer co
Fabrication and properties of cellulose hydrated membrane with unique structure
Reversibly switchable double- responsive block copolymer brushes
Electrospinning of thermo-regulating ultrafine fibers based-on polyethylene glycol/cellulose acetate
Morphology and thermal properties of electrospun fatty acids/polyethylene terephthalate composite fi
Facile creation of biomimetic systems at the interface and in bulk
Arrangement of cellulose microfibrils in the wheat straw cell wall
Synthesis of graft copolymer of ethyl cellulose through living polymerization and its self-assembly
Molecular weight dependence of the poly(L- lactide)/poly(D-lactide) stereocomplex at the air- water
Simulation of sessile water-droplet evaporation on superhydrophobic polymer surfaces
Self-organized polymer aggregates with a biomimetic hierarchical structure and its superhydrophobic
Melting behavior of lamellae of isotactic polypropylene studied using hot-stage atomic force microsc
Epitaxial Crystallization of Isotactic Poly(Methyl Methacrylate) on Highly Oriented Polyethylene
Electrospinning of native cellulose from nonvolatile solvent system
Porphyrin-dithienothiophene π-conjugated copolymers: Synthesis and their applications in field-effec
Hyperbranched polymer-cored star polyfluorenes as blue light-emitting materials
Triphenylamine-based dyes for dye-sensitized solar cells
Promising founctional materials base on ladder polysiloxanes
Hierarchical self-assembly of p-terphenyl derivative with dumbbell-like amphiphilic and rod-coil cha
Evaporation of sessile water droplets on superhydrophobic natural lotus and biomimetic polymer surfa
Tuning the Optical Properties of Hyperbranched Polymers through the Modification of the End Groups
On the development of special positive isotactic polypropylene spherulites
Shear-induced interfacial structure of isotactic polypropylene (iPP) in iPP/fiber composites
超疏水表面的研究进展
仿生材料电活性聚合物“人工肌肉”的研究进展
聚环氧乙烷-g-聚己内酯两亲性接枝共聚物的合成及药物释放行为
聚合物流体的范德华凝聚行为
长链支化聚丙烯和线性聚丙烯熔体结晶动力学的对比研究
熔体拉伸聚乙烯超薄膜的结构表征
木质素磺酸盐在UV／H2O2下的降解
A comparison study on the melt crystallization kinetics of long chain branched and linear isotactic polypro- pylenes
Effect of crystallization temperature and propylene sequence length on the crystalline structure of propylene-ethylene random copolymers
会议论文
What is nano-effect for polyurethane-clay composites
Bionic polymer surfaces with Louts-like Micro- and Nano-binary Structure
Bio-inspired Versatile Locomotion of Polymer Gel in Air
Fabrication and Properties of Biodegradable Polymeric Microspheres As Cell Growth Microcarriers
Melting of Polymer Crystals in Nano-domains: Size matters
新材料在汽车中的应用
Three-dimensional conjugated polymers as efficient light-emitting materials
Facile Fabrication of Biomimetic Superhydrophobic Surfaces
Structure Controlling of Biodegradable Polymeric Materials
Synthesis, Characterization and Microsphere Fabrication of Biodegradable Block Copolymers Containing
有机－无机杂化材料－聚倍半氧烷杂化材料的研究
国产高性能碳纤维研发和工程化进展
高性能PAN碳纤维基础科学问题与高技术研发
超高分子量部分水解聚丙烯酰胺的GPC表征
高性能聚丙烯腈PAN碳纤维基础科学问题
Hydrogen-Bonded Film from PVPON and PAA
A Novel Ultra-Hydrophobic Surface: Statically on-Wetting but Dynamically Non-Sliding
Star and Hyperbranched Conjugated Polymers as Effective Light-Emitting Materials
Synthesis and assembly of grafting copolymers based on cellulose chains
Electrospinning of Hyaluronic acid (HA) and HA/Gelatin Blends
Origin of oriented recrystallization of carbon coated pre-oriented ultra thin polymer films
材料的软物质特性及智能响应行为
天然高分子双亲性接枝共聚物的制备与自组装
高分子仿生表面的软物质特性
复合功能中空微球
Field-driven gel actuator with locomotion in air
Chemical Modification and Properties of Biodsegradable Polymers
Assembly of metal nanoparticles on cellulose microcrystals
A stimule-responsive fluorescent probe
Native cellulose microfibrils template for self-assembly of silver nanoparticles
高性能PAN碳纤维基础科学问题与关键技术研发
What is The Nano-Effeet for Polyurethane-Clay Composite
高性能碳纤维与复合材料发展趋势
Antireflective Functional Film for Solar cell
Electrospun polyethylene glycol/cellulose acetate ultrafine fibers for thermal energy storage
Electrospinning of Natural Polymers1
Hierarchically Supramolecular Self-Assembly of Nanotubes and Layered Sheets
超疏水涂层的结构设计和应用
高性能聚丙烯腈PAN碳纤维基本科学问题的思考
高分子软物质特性研究与同步辐射表征新方法探索
仿生高分子材料研究的新进展
高分子凝胶及其相互作用的研究
Electrospinning of thermo-regulating ultrafine fibers based on polyethylene glycol/cellulose acetate
Self-assembly with controllable micellar size based on ethyl cellulose dense grafting polystyrene co
中国碳纤维的研发进展、面临挑战与发展趋势
高性能PAN碳纤维基础科学问题与技术研发
高分子仿生表面制备、形貌和特性的研究
Bionic Superhydrophobic Polymer Surfaces With Nano-Micro-Binary Structure
高分子材料的生物降解研究
聚合物的多重熔融行为研究
Orientation induced beta crystallization of iPP
Crystallization of synsiotactic polystyrene in atactic polystyrene networks
Thermosensitive Amphiphilic Copolymers of Ethyl Cellulose-graft-P(PEGMA) Synthesized via ATRP
Facile Creation of Biomimetic Systems at Interface
Important Chemical Materials in China
2008新材料课题指南研读
Hydrogen-Bonded Film From PVPON/PAA - Fundamental and Application of poly(vinylpyrrolidone)/poly(acr
高分子材料的软物质特性和应用
Study of Polymer Enzymatic Degradation
Synthesis of amphiphilic ethyl cellulose grafting poly (acrylic acid) copolymers by atom transfer ra
Three-dimensional conjugated polymers as efficient light-emitting materials
Orientation induced β crystallization of iPP
Fabrication of superhydrophobic surfaces with lotus-like nano- and micro- binary microstructure
聚合物多层次结构构筑与调控中的基本软物质科学问题
新型抗反射薄膜在太阳能组件上的应用
In-situ investigation of gelation and molecular diffusion in hydrogels
Overview on Developing Advanced Materials in China
Development of Advanced Materials and Technology in China
Art And Sciences Learning from Nature- A Story of Bionic Polymer Materials
高分子仿生表面的软物质特性
著作
高性能结构材料丛书（7本,共计347万字）
仿生高分子
高分子－从天然到人工
第八章，智能与仿生高分子材料
显微学最新进展——三维结构重构技术
黄勇的项目
生物质的结构和形态及其结构构筑
期刊论文 9 会议论文 4
具有手性结构膜的制备与性能
期刊论文 8 会议论文 4
2004美国物理学春季年会
高分子材料多层次结构及结构调控
期刊论文 153 会议论文 59 专利 24
以纤维素为基的双亲性接枝共聚物的合成与组装
期刊论文 12 会议论文 8