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中文摘要：
金属冠醚是结构、功能与有机冠醚相似的一类含有金属原子的大环分子。金属冠醚呈现出有机冠醚没有的一些特性，如光谱性质、磁性及氧化还原性质等，其应用已扩展到化学修饰电极、阴离子选择性分离、液晶、纳米材料前体、分子识别、生物无机化学和主客体与超分子化学等领域。近年来, 配位聚合物的晶体工程已成为配位化学、超分子化学、材料和生命科学等现代化学的研究热点和迅猛发展的研究领域。金属冠醚中金属原子多，与配体的结合点也多。在研究冠醚-金属配位聚合物的基础上，我们拟利用金属冠醚作为构筑配位聚合物的"砖块（building block）"，与不同的金属、中性配体、阴离子配体等反应，设计合成系列一维、二维和三维金属冠醚配位聚合物。分别对它们的结构与磁性、生物活性和阳离子识别等性质作深入研究，得出其合成规律、结构特点、性质及结构-性质关系。既为该类聚合物的合理设计提供思路，也为该领域的实际应用提供依据及信息。
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期刊论文
A mixed-type of azametallacrown containing [Mn6(pnhz)6(DMF)4(H2O)2] and [Mn6(pnhz)6(DMF)2(H2O)4] con
[μ-1,2-Disalicyl hydrazine(2–)-k3 N,O,O': k3 N',O'',O''']bis[tripyridinenickel(II)] pyridine disolva
New lead complexes of 2-hydroxymethylpyridine ligand: supramolecular structures based on π···π or co
[μ-1,2-Bis(2-hydroxybenzoyl)hydrazine)]bis [tripyridinecobalt(II)]bis[trichloridopyridinecobalt(III)
A novel ferromagnetic Mn4(II) complex: [Mn4(hmp)4(dcn)4]n (where Hhmp = 2-hydroxymethylpyridine, dcn
Dimethyl 2,5-bis[2-(2-hydroxybenzoyl) hydrazino] cyclohexa-1,4-diene-1,4- dicarboxylate dimethylform
A 2-D metal-organoic framework of the iron-based 18-metallacrown-6 with N-(methyl-maleamic ester) te
Synthesis and supramolecular structure of Zn, Cd, Hg complexes constructed by 2,3-naphtho-15-crown-5
Synthesis, characterization and crystal structure of two manganese metallacrowns: 30-metallacrown-10
A novel 9-MC-3 and 15-MC-6 on-set stacked metallacrown: Synthesis, crystal structure and single-mole
会议论文
Synthesis and crystal structure of nickel complex containing N- benzeneacetyl-5-chlorosalicylichydra
Synthesis, characterization and crystal structure of a 2D mixed-metal Fe(III)/Na(I) complex built on
Synthesis and crystal struture for an iron complex [Fe3(L)3(Py)3?(SO4)?(OH)] L= (2-hydroxyacetopheno
Synthesis and characterization of copper complex containing acetylpyridine -5-chlorosalicylichydrazo
Synthesis and structural characterization of three- dimension network of {[Na2(PyDA)2 (PyDHA)2·2H2O]
Synthesis and crystal structure of cobalt complex containing N-trifluoroacetyl-4-hydroxysalicylhydra
Synthesis and crystal structure of a novel anti 12-metallacrown-4 zinc (Ⅱ) complex with phenyl 2-pyr
Synthesis and crystal structure of 3D supramolecular complex: [Zn4(HL)2 (OAc)6]·2H2O (HL = di-2-pyri
Synthesis and crystal structure of 9-metallacrown-3 copper (II) complex with phenyl 2-pyridyl ketone
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