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中文摘要：
选择具有开壳层电子结构和平面型分子结构的多硫烯胺配阴离子作为电荷和自旋载体，利用其易形成面对面二聚结构的特点，设计分子几何可塑性强、抗磁性的苄基吡啶衍生物作为对阳离子，通过化学修饰，调节阳离子的分子构象，诱导相邻的阴离子二聚体通过多硫烯胺配体的侧位或端基上硫、氧、氮原子之间的弱相互作用，构筑低维分子磁性材料，研究其结构和磁、电功能性。将金、镍离子混合与多硫烯酰胺形成配阴离子，通过控制其摩尔比，实现对分子磁性材料的相互掺杂，研究掺杂后分子磁性材料的结构、磁学和电学性质。进一步研究分子磁性材料在高压下的磁电功能性。本申请项目是分子设计和剪裁在功能性分子基材料定向合成方面的探索。很可能在高温有机超导体、低维磁相变材料领域获得极有意义的结果。
英文摘要：
Magnetic materials；Dithiolene；Crystal structure；Coordination polymer；Ferroelectric properties
结论摘要：
在本项目中，我们开展了低维分子磁性材料设计、合成和构效关系研究以及功能配位聚合物的设计、合成和性质研究工作。（1）合成了三类具有柔性分子构象的有机阳离子（苄基吡啶阳离子、苄基喹啉阳离子和氨基吡啶烷基链阳离子），将其作为磁性双-（二硫烯）过渡金属配位阴离子的平衡离子。通过系统地改变阳离子芳环上取代基的立体和电子性质，或者系统地改变烷基链长，以及调控结晶溶剂的极性、配位能力等溶剂性质，控制磁性双-（二硫烯）过渡金属配位阴离子形成一维柱状堆积，得到了本项目的目标化合物，结合理论研究，建立了阳离子堆积结构-阴离子排列方式与性质之间的相关性。此外，我们还选择了另外两种分子磁性模块（TCNQ、dbt）和上述结构控制块反应，合成一系列低维分子磁性材料。该研究发现，在TCNQ体系中，结构控制块中苯环上的取代基对TCNQ阴离子的排列方式影响不大，而吡啶环上取代基对结构起着决定性作用，并从理论上研究了结构与性质之间的关系。在dbt体系中，苯环和吡啶环上取代对Ni(dbt)2阴离子排列方式影响不大。（2）探索各种反应条件对配位聚合物结构的影响，然后在此基础上合成了一系列具有荧光性质、磁性铁电性质、液晶性质的功能材料，研究了它们的结构和性质，探索了它们的结构和性质之间的关系。
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期刊论文
A Six-Connected 3D Europium Coordination Polymer Assembled by 5-Bromoisophthalic Acid (H(2)BIPA) and
Construction of hybrid d(10) metal-organic frameworks by flexible aromatic dicarboxylate and N-donor
Synthesis, Structure and Luminescent Properties of a New Terbium(III) Complex with 5-Bromoisophthali
Syntheses, Structures and Luminescent Properties of Zinc(II) and Cadmium(II) Complexes With the Dito
Synthesis, Crystal Structure and Magnetic Properties of a Novel Copper Inverse-9-metallacrown-3 Comp
Hydrothermal Synthesis, Crystal Structure and Magnetic Properties of a Novel Cobalt Complex Based on
Synthesis, Crystal Structure and Photoluminescent Property of 2D Layer Coordination Polymer [CdCl2(o
Hydrothermal Synthesis, Crystal Structure and Magnetic Properties of Lithium Manganese Complex of Be
Synthesis, structure and near-infrared luminescence of a new 2D praseodymium(III) coordination polym
A New Chiral Cu(II) Complex Consisting of Achiral Flexible Tripodal Ligand of Benzene-1,3,5-Triaceta
An unusual two-dimensional 2-fold interpenetrating metal-organic framework based on tetranuclear man
A chiral copper(II) inverse-9-metallacrown-3 complex: Synthesis, crystal structure, ferroelectric an
Synthesis and Crystal Structure of a Novel Heterometallic Complex with 1,2,4,5-Benzenetetracarboxyli
Hydrothermal Synthesis, Crystal Structure and-Photoluminescence of a New Two-Dimensional Cadmium(II)
Synthesis, characterization, and crystal structures of two novel ion-pair complexes based on benzene
Hydrothermal Synthesis, Crystal Structure and Photoluminescence of a Novel Two-Dimensional Cadmium(I
Synthesis, Crystal Structure, and Magnetic Property of a New Nickel(III) Complex Constructed from 1,
Hydrothermal Synthesis, Crystal Structure and Photoluminescence of a Novel Three-Dimensional Zinc(II
Hydrothermal Synthesis, Crystal Structure and Photoluminescence of a Novel One-Dimensional Cadmium(I
A Trinuclear Cu(II) Complex from the Use of Phenyl 2-Pyridyl Ketoxime: Structure and Magnetic Behavi
New Photoluminescent Coordination Polymers Constructed from Dicarboxylate and 1,2-Bis(imidazol-1-ylm
Self-assembly of 3-D 4d-4f coordination frameworks based on pyridine-3,5-dicarboxylic acid: Synthese
Five 3D metal-organic frameworks constructed from V-shaped polycarboxylate acids and flexible imidaz
Synthesis, Crystal Structure, Electronic Absorption and Magnetic Properties of a Novel Anion-Radical
Synthesis, structure and photoluminescent properties of a new Eu(III) complex with 5-bromoisophthali
Synthesis, structure and magnetic properties of a pentanuclear Cu(II) coordination polymer with 4-(i
Synthesis, Crystal Structure and Magnetic Property of 2D Coordination Polymer {[Cu-2(BIPA)(2)(bpe)(2
A Porous 4d-4f Heterometallic Coordination Polymer: Synthesis, Crystal Structure and Physical Proper
Construction of two metal coordination polymers based on 1,4-terephthalate and 1,4-bis(1,2,4-triazol
Synthesis, Crystal Structure and Fluorescent Property of a Cadmium(II) Coordination Polymer Construc
Syntheses, structures and photoluminescent properties of two zinc(II) coordination polymers based on
Three new nickel(III) compounds based on 2-thioxo-1,3-dithiole-4,5-dithiolate: Syntheses, structures
Syntheses, Crystal Structures and Fluorescent Properties of Zinc Coordination Polymers Based on Camp
Three zinc(II) complexes constructed from aromatic dicarboxylate and 1,4-bis((2-(pyridin-2-yl)-1H-im
Synthesis and Crystal Structure of a Cobalt(II) Coordination Polymer with Benzene-1,3,5-triacetate a
A 4d-4f heterometallic coordination polymer: Synthesis, crystal structure and near-infrared luminesc
Syntheses, Structures, and Luminescent Properties of two Cadmium(II) Entangled Frameworks Based on 5
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