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中文摘要：
建立和发展新型大环主体分子的超分子化学对发现和揭示分子间非共价键相互作用、构建分子(自）组装体系和纳米结构、发展高效和高灵敏的分子识别试剂、深刻认识生命体系中的化学过程等具有重要的理论意义和实际使用价值。因此，探索构筑新型功能性大环主体化合物一直是超分子科学研究的核心，是丰富超分子科学的内容和推动超分子科学发展的动力和创新源泉。本项目旨在建立和发展具有我们自己特色的、结构新颖和功能多样的大环主体分子体系的超分子化学。具体研究杂原子桥连杯（杂）芳烃或环蕃及其类似物和衍生物、以及基于三蝶烯（醌）结构单元的大环主体分子的设计与合成；并以它们为平台，研究其衍生化反应性能，合成具有多功能化的大环主体分子；研究所合成的大环主体分子在固态下和溶液中的结构与构象；研究它们对阳离子、阴离子和中性分子的识别性能，发展超分子传感器；构筑新型的（固有）手性大环分子，研究它们对于手性分子的识别性能。
结论摘要：
英文主题词Supramolecular chemistry, macrocyclic host melocules, molecular recognition, heteroatom bridged calixarenes, triptycene-besed host molecule
成果综合统计
期刊论文
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期刊论文
Synthesis, structures, and properties of peripheral o-dimethoxy-substituted pentiptycene quinones an
Self-assembly of triptycene-based cylindrical macrotricyclic host with dibenzylammonium ions: Constr
A triptycene-based bis(crown ether) host: Complexation with both paraquat derivatives and dibenzylam
Efficient potassium-ion-templated synthesis and controlled destruction of [2]rotaxanes based on casc
A [2+3] fragment coupling approach to N,O-bridged calix[1]arene[4]pyridines and their complexation w
Synthesis of (NH)(m)(NMe)(4-m)-Bridged Calix[4]pyridines and the Effect of NH Bridge on Structure an
Room-temperature aerobic formation of a stable aryl-Cu(III) complex and its reactions with nucleophi
Triptycene-Derived N(H)-Bridged Azacalixarenes: Synthesis, Structure, and Encapsulation of Small Neu
Complexation of a Pentiptycene-Based Tweezer-Like Receptor with Paraquat Derivatives: Ion-Controlled
A pentiptycene-based bis(crown ether) host: synthesis and its complexation with cyclobis(paraquat-p-
Highly selective synthesis of triptycene o-quinone derivatives and their optical and electrochemical
Synthesis and structure of nitrogen bridged calix[5]- and -[10]-pyridines and their complexation wit
Formation and conformational conversion of flattened partial cone oxygen bridged calix[2]arene[2]tri
Selective templated complexation of a cylindrical macrotricyclic host with neutral guests: Three cat
Highly selective recognition of diols by a self-regulating fine-tunable methylazacalix[4]pyridine ca
Complexation of triptycene-based cylindrical macrotricyclic polyether toward diquaternary salts: Ion
Synthesis and structure of upper-rim 1,3-alternate tetraoxacalix[2]arene[2]triazine azacrowns and ch
Guest-dependent complexation of triptycene-based macrotricyclic host with paraquat derivatives and s
Efficient synthesis of a chiral [4]pseudocatenane and its derivatives: A novel ship's wheel-like int
Novel triptycene-based cylindrical macrotricyclic host: Synthesis and complexation with paraquat der
Synthesis of tetraazacalix[2]arene[2] triazines: Tuning the cavity by the substituents on the bridgi
会议论文
Heteroatom bridged calixaromatics novel and versatile macrocyclic host molecules in supramolecular c
Novel Triptycene-Derived Hosts : Synthesis and Their Applications in Molecular Recognition and Assem
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