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中文摘要：
多孔材料和纳米材料均具有巨大的比表面积并可提供较多的活性位点，因此可以对材料的光、电、磁等性质产生重要影响。本项目以微孔晶体和无机纳米粒子两类材料为主体，运用多种组装及相关复合手段，制备了一系列无机复合体系。包括微孔孔道中的非常规价态和结构的金属离子或离子簇、具有特殊组成及形貌的半导体微纳复合材料、特定结构的无机-有机复合体系以及以生物质为原料制备的新型多孔材料等。在制备和表征的基础上，以功能为导向深入挖掘各体系的组成、结构和性能之间的关系。根据微孔晶体及纳米材料的特性，对获得的复合体系的存在状态以及相关化学反应特性进行解析；系统地研究这两类无机复合体系中主-客体组分间的相互作用和复合体系的化学物理性质，对无机复合体系在催化转换、能源利用、环境治理等方面的功能进行探索与开拓。本研究对于揭示各类主客体间的物理化学作用规律、指导开发新型功能化的无机复合体系具有重要的意义。
结论摘要：
英文主题词Composite systems; microporous crystals;
成果综合统计
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期刊论文
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Synthesis, structure characterization and photocatalytic properties of two new uranyl naphthalene-di
Preparation and Tunable Photoluminescence of Carbogenic Nanoparticles Confined in a Microporous Magn
The effect of Al(3+) treatment on charge dynamics in dye-sensitized nanocrystalline TiO(2) solar cel
Montmorillonite-Supported Ag/TiO(2) Nanoparticles: An Efficient Visible-Light Bacteria Photodegradat
General Synthesis of Uniform Metal Sulfide Colloidal Particles via Autocatalytic Surface Growth: A S
Hierarchical porous carbon derived from rice straw for lithium ion batteries with high-rate performa
Carbon anode material formed from template molecules occluded in a magnesium-substituted aluminophos
Magnetically recyclable Ag-ferrite catalysts: general synthesis and support effects in the epoxidati
Decoration of multiwalled carbon nanotubes with CoO and NiO nanoparticles and studies of their magne
Effect of Heterojunction on the Behavior of Photogenerated Charges in Fe(3)O(4)@Fe(2)O(3) Nanopartic
Direct conversion of urea into graphitic carbon nitride over mesoporous TiO(2) spheres under mild co
Synthesis of SnO(2) hollow nanostructures with controlled interior structures through a template-ass
Preparation and gas storage of high surface area microporous carbon derived from biomass source corn
Effects of raw material texture and activation manner on surface area of porous carbons derived from
Heterometal alkoxides as precursors for the preparation of porous Fe- and Mn-TiO2 photocatalysts wit
Synthesis of uranium oxide nanoparticles and their catalytic performance for benzyl alcohol conversi
Preparation, structures, and photocatalytic properties of three new uranyl-organic assembly compound
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