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中文摘要：
本项目利用扫描探针显微技术结合电化学循环伏安技术、扫描隧道谱和理论计算等技术对非共价键在有机分子组装组织中的存在形式、结构类型以及对组装结构的影响进行了深入系统的研究，探索了同类分子间、不同类分子间非共价键作用力对多种有机功能分子组装的影响规律，发现分子组装结构中非共价键作用以范德华力、氢键、卤键、偶极－偶极作用等多种形式存在，对分子组装结构的形成与稳定有着重要作用；揭示了各种非共价键作用及分子与基底间的作用在分子组装结构的形成中相互制约、依存和转化的关系与规律，并利用这些分子间非共价键的弱相互作用力实现了功能性分子纳米结构的可控构筑。发表文章43篇，完成项目总体预定目标。
结论摘要：
英文主题词molecular self-assembly; weak interaction; noncovalent bond; scanning tunneling microscopy
成果综合统计
期刊论文
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期刊论文
Hydrogen Bond Partner Reorganization in the Coadsorption of a Monodendron and Pyridylethynyl Derivat
Structure and structural transition of chiral domains in oligo(p-phenylenevinylene) assembly investi
In Situ Scanning Tunneling Microscopy of Solvent-Dependent Chiral Patterns of 1,4-Di[4-N-(trihydroxy
Self-assembly and aggregation of melamine and melamine-uric/cyanuric acid investigated by STM and AF
Surface Confined Metallosupramolecular Architectures: Formation and Scanning Tunneling Microscopy Ch
One Solvent Induces a Series of Structural Transitions in Monodendron Molecular Self-Assembly from L
Fabrication and Manipulation of Molecular Nanostructure with Metal-Coordinated Compound on Solid Sur
Chiral Kagome Network from Thiacalix[4]arene Tetrasulfonate at the Interface of Aqueous Solution/Au(
Solvent-Controlled 2D Host-Guest (2,7,12-Trihexyloxytruxene/Coronene) Molecular Nanostructures at Or
Engineering of Linear Molecular Nanostructures by a Hydrogen-Bond-Mediated Modular and Flexible Host
Theoretical understanding of adlayer structure, thermal stability and electronic property of graphen
Formation and structural transition of molecular self-assembly on solid surface investigated by scan
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