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中文摘要：
绿色有机化学的主要研究目标是发现环境友好的新反应、新方法，开发或应用新型绿色催化剂、介质、试剂或原料及其新技术，尽可能地实现化学反应的绿色化。本申请项目是2007年结题的国家自然科学基金重点项目"环境友好介质中有机反应的研究"的拓展与深化。将以绿色化学基本原理为指导，针对碳－碳键、碳－杂原子键选择性断裂与可控性组合的一些重要有机化学反应，研究开发适合于环境友好介质与试剂的新型催化体系，探索绿色介质、催化剂、反应底物之间的耦合规律与协同效应，以及相互作用机制，发展绿色化学导向的一些新反应、新方法、新理论、新技术，促进绿色有机化学的发展。该项研究具有重要的理论意义和实际意义。
英文摘要：
Green Chemistry；Synthetic Methodology；Supported Catalyst；Selectivity；Organic Reaction
结论摘要：
项目已按“计划任务书”顺利完成了各项研究任务。项目成功设计、制备了不同类型的负载型新型催化剂并应用于氧化反应、氢化反应等，提高了催化效率和实现了催化剂的重复利用，发展了分子氧为单一氧化剂的不饱和烃氧化反应新方法，发展了炔卤、异腈作为合成子的系列新型有机反应，开发出一些新型的多米诺反应用于高效合成含氧含氮杂环化合物，开拓了电化学有机合成方法学研究，发展了二氧化碳转化利用的新方法。这些研究在碳－碳键、碳－杂原子键选择性断裂与可控性组合过程中融入了绿色催化剂、清洁氧化剂、高效催化与原子经济性等绿色化学内涵，促进了绿色有机合成化学的发展。项目已经发表SCI论文 180 篇，其中二区以上的文章 128 篇，包括Acc. Chem. Res. 1 篇，J. Am. Chem. Soc. 2 篇，Angew. Chem. Int. Ed. 7 篇，Chem. Sci. 3 篇，Org. Lett. 21 篇，J. Org. Chem. 21 篇，Chem. Commun. 25 篇，Chem. Eur. J./Chem. Asia J. 15 篇，Adv. Synth. Catal. 7 篇，Green Chem. 12 篇，被SCI他引 1243 次，多篇文章被SYNFACTS等刊物专题评述。申请和授权专利 8 项，在国内外学术会议和双边会议上作报告 20 余次，项目已经培养（毕业）博士生 34 人，硕士生 16 人，其中1人获得全国优秀博士论文提名奖，3 人获广东省/中国科学院优秀论文奖，3 人获教育部博士研究生学术新人奖。项目组获得国家自然科学奖二等奖和广东省科学技术奖励一等奖各 1 项，教育部长江学者和创新团队发展计划创新团队项目 1 项。
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期刊论文
Pd-catalyzed and CsF-promoted reaction of bromoalkynes with isocyanides: regioselective synthesis of
Switch of Selectivity in the Synthesis of alpha-Methylene-gamma-Lactones: Palladium-Catalyzed Interm
Chlorine-free copper-catalyzed oxidative synthesis of 1,3,4-oxadiazoles with molecular oxygen as the
Acetoxypalladation of unactivated alkynes and capture with alkenes to give 1-acetoxy-1,3-dienes taki
A new three-dimensional metal-organic framework constructed from 9,10-anthracene dibenzoate and Cd(I
Palladium-Catalyzed Intermolecular Dehydrogenative Anninohalogenation of Alkenes under Molecular Oxy
Nano-Cu(2)O-Catalyzed Formation of C-C and C-O Bonds: One-Pot Domino Process for Regioselective Synt
Carbon Dioxide Triggered and Copper-Catalyzed Domino Reaction: Efficient Construction of Highly Subs
Palladium-Catalyzed Alkenylation of 1,2,3-Trizoles with Terminal Conjugated Alkenes by Direct C-H Bo
One-Pot Silver-Catalyzed and PIDA-Mediated Sequential Reactions: Synthesis of Polysubstituted Pyrrol
Expedient Synthesis of Functionalized Conjugated Enynes: Palladium-Catalyzed Bromoalkynylation of Al
Tris(4-anisyl)phosphine as an Efficient and Practical Reagent for the Synthesis of (E)-2-Benzylidene
Practical Synthesis of Polysubstituted Imidazoles via Iodine- Catalyzed Aerobic Oxidative Cyclizatio
Copper-catalyzed electrochemical synthesis of alkylidene lactones from carbon dioxide and 1,4-diaryl
Copper-Catalyzed Synthesis of Substituted Benzothiazoles via Condensation of 2-Aminobenzenethiols wi
Pd(II)-Catalyzed Sequential C-C/C-O Bond Formations: A New Strategy to Construct Trisubstituted Fura
Palladium-Catalyzed Bond Reorganization of 1,3-Diynes: An Entry to Diverse Functionalized 1,5-Dien-3
Synthesis of 2-Aminobenzoxazoles and 3-Aminobenzoxazines via Palladium-Catalyzed Aerobic Oxidation o
A New Series of C-6 Unsubstituted Tetrahydropyrimidines: Convenient One-Pot Chemoselective Synthesis
Ni(salphen)-based metal-organic framework for the synthesis of cyclic carbonates by cycloaddition of
Copper (I) catalyzed synthesis of 1,3-oxazolidin-2-ones from alkynes, amines, and carbon dioxide und
Palladium(II)-Catalyzed Highly Regio- and Stereoselective Synthesis of 2-Chloro-1,3-diene Derivative
Synthesis of 4H-cyclopenta[c]furans via cooperative PdCl2-FeCl2 catalyzed cascade cyclization reacti
A mixed-valence lanthanide metal-organic framework, templated by 2,2 '-bipyridine formed in situ rea
Palladium-Catalyzed Sequential Formation of C-C Bonds: Efficient Assembly of 2-Substituted and 2,3-D
Carbon-Carbon Bond Formation: Palladium-Catalyzed Oxidative Cross-Coupling of N-Tosylhydrazones with
Synthesis, Structures, and Properties of Two Three-Dimensional Metal-Organic Frameworks, Based on Co
Access to C(sp(3))-C(sp(2)) and C(sp(2))-C(sp(2)) Bond Formation via Sequential Intermolecular Carbo
Copper(I)-Catalyzed Synthesis of 2,5-Disubstituted Furans and Thiophenes from Haloalkynes or 1,3-Diy
Synthesis of delta-Bromo gamma,delta-Unsaturated Carbonyl Compounds via Palladium-Catalyzed Bromoalk
A novel asymmetric di-Ni(II) system as a highly efficient functional model for phosphodiesterase: sy
Pd-Catalyzed cyclization reaction: a convenient domino process for synthesis of alpha-carbonyl furan
Palladium-Catalyzed Bromoalkynylation of C-C Double Bonds: Ring-Structure-Dependent Synthesis of 7-A
Highly regio- and stereoselective synthesis of 1,3-enynes from unactivated ethylenes via palladium-c
Palladium-Catalyzed Carbonation-Diketonization of Terminal Aromatic Alkenes via Carbon-Nitrogen Bond
Effective synthesis of symmetrical oxygen- and nitrogen-heterocycles from electron-deficient alkynes
An aerobic [2+2+2] Cyclization via Chloropalladation: From 1,6-Diynes and Acrylates to Substituted A
Facile Synthesis of (E)-Alkenyl Aldehydes from Allyl Arenes or Alkenes via Pd(II)-Catalyzed Direct O
DABCO-Catalyzed Oxidation of Deoxybenzoins to Benzils with Air and One-Pot Synthesis of Quinoxalines
Palladium-Catalyzed Cross-Coupling Reactions of Electron-Deficient Alkenes with N-Tosylhydrazones: F
Hydrogenation of methyl laurate to produce lauryl alcohol over Cu/ZnO/Al2O3 with methanol as the sol
Synthesis of unsymmetrical organic carbonates catalyzed by zirconium phosphonate functionalized with
Elimination of the negative effect of nitrogen compounds by CO2–water in the hydrocracking of anthra
Regioselective Oxyalkylation of Vinylarenes Catalyzed by Diatomite-Supported Manganese Oxide Nanopar
Selective Iodine-Catalyzed Intermolecular Oxidative Amination of C(sp3)H Bonds with ortho-Carbonyl-S
A Highly anti-Selective Asymmetric Henry Reaction Catalyzed by Chiral Copper Complex and Application
Highly active and selective synthesis of imines from alcohols and amines or nitroarenes catalyzed by
Electrochemical tandem synthesis of oximes from alcohols using KNO3 as the nitrogen source, mediated
Synthesis, structures, and luminescent properties of four new 3D lanthanide metal-organic frameworks
Silver-Assisted Difunctionalization of Terminal Alkynes: Highly Regio- and Stereoselective Synthesis
Palladium-Catalyzed CC Coupling of Aryl Halides with Isocyanides: An Alternative Method for the Ster
Pd(II) immobilized on mesoporous silica by N-heterocyclic carbene ionic liquids and catalysis for hy
Synthesis of cyclic carbonates and dimethyl carbonate using CO2 as a building block catalyzed by MOF
Enantioselective and Regioselective Friedel–Crafts Alkylation of Pyrroles with Nitroalkenes Catalyze
Multi-functional Metal-organic frameworks based on H4mdip: crystal structure, photoluminescence, sel
Four new metal–organic frameworks constructed from H2DBTDC-O2 (H2DBTDC-O2 ? dibenzothiophene-5,50-di
Highly Enantioselective Henry Reaction in Water Catalyzed by a Copper-Tertiary Amine Complex and App
Highly efficient synthesis of 2,3,4-trisubstituted furans via silver-catalyzed sequential nucleophil
Copper-Catalyzed Aerobic C(sp(2))-H Functionalization for C-N Bond Formation: Synthesis of Pyrazoles
Facile synthesis of benzofurans via copper-catalyzed aerobic oxidative cyclization of phenols and al
Facile Synthesis of Trisubstituted Allenynes by Phosphane-Mediated Deoxygenation of 2,4-Pentadiyn-1-
Iron-Catalyzed Domino Process for the Synthesis of alpha-Carbonyl Furan Derivatives via One-Pot Cycl
Silver-Catalyzed Difunctionalization of Terminal Alkynes: Highly Regio- and Stereoselective Synthesi
Palladium-Catalyzed Direct Oxidation of Alkenes with Molecular Oxygen: General and Practical Methods
PdCl2(HNMe2)(2)-Catalyzed Highly Selective Cross [2+2+2] Cyclization of Alkynoates and Alkenes under
Synthetic Approach to Polysubstituted Furans: An Efficient Addition/Oxidative Cyclization of Alkynoa
Silver-Catalyzed One-Pot Cyclization Reaction of Electron-Deficient Alkynes and 2-Yn-1-ols: An Effic
An Efficient Synthesis of Polysubstituted Pyrroles via Copper-Catalyzed Coupling of Oxime Acetates w
Facile Synthesis of Dibranched Conjugated Dienes via Palladium-Catalyzed Oxidative Coupling of N-Tos
Palladium-Catalyzed Oxidative Coupling of Aromatic Primary Amines and Alkenes under Molecular Oxygen
Copper-Catalyzed Intermolecular Oxidative Cyclization of Haloalkynes: Synthesis of 2-Halo-substitute
Aerobic Oxidative Coupling between Carbon Nucleophiles and Allylic Alcohols: A Strategy to Construct
Facile one-pot synthesis of VxOy@C catalysts using sucrose for the direct hydroxylation of benzene t
Catalytic hydroxylation of benzene to phenol with hydrogen peroxide using catalysts based on molecul
Theoretical study on the reaction of CO2 and 2-aminobenzonitrile to form quinazoline-2,4(1H,3H)-dion
Cobalt-catalyzed oxidative [3 + 2] cycloaddition reactions: an efficient synthesis of pyrrolo- and i
Metal-free synthesis of polysubstituted oxazoles via a decarboxylative cyclization from primary &alp
A Highly Tunable Stereoselective Dimerization of Methyl Ketone: Efficient Synthesis of E- and Z-1,4-
Iron-Catalyzed Synthesis of 2-Vinylquinolines via sp3 CH Functionalization and Subsequent CN Cleavag
A Rapid and Efficient Access to Polysubstituted Imidazoles via Iodine-Catalyzed Tandem Oxidative Cyc
Natural alpha-amino acids applied in the synthesis of imidazoles[1,5-a]N-heterocycles under mild con
Palladium-assisted multicomponent cyclization of aromatic aldehydes, arylamines and terminal olefins
Immobilized 1,1,3,3-Tetramethylguanidine Ionic Liquids as the Catalyst for Synthesizing Propylene Gl
Efficient synthesis of quinazoline-2,4(1H,3H)-diones from CO2 and 2-aminobenzonitriles in water with
Synthesis of Chromones through LiOtBu/Air-Mediated Oxidation and Regioselective Cyclization of o-Hyd
Copper-Catalyzed Formal C-N Bond Cleavage of Aromatic Methylamines: Assembly of Pyridine Derivatives
Direct Arylation of Imidazo[1,2-a]pyridine at C-3 with Aryl Iodides, Bromides, and Triflates via Cop
Metal-Free Synthesis of 2-Aminobenzothiazoles via Aerobic Oxidative Cyclization/Dehydrogenation of C
Highly selective synthesis of phenol from benzene over a vanadium-doped graphitic carbon nitride cat
Transition-Metal-Catalyzed Domino Reactions: Efficient One-Pot Regiospecific Synthesis of Highly Fun
Palladium-catalyzed tandem reaction of o-aminophenols, bromoalkynes and isocyanides to give 4-amine-
A chiral mixed metal-organic framework based on a Ni(saldpen) metalloligand: synthesis, characteriza
Pd(II)-Catalyzed Highly Regio- and Stereoselective Assembly of C-C Double Bonds: An Efficient Method
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