欢迎您！东篱公司
退出
-
申报数据库
-
立项数据库
-
成果数据库
-
项目获奖数据库
中文摘要：
本文主要介绍了近5年来超临界二氧化碳中有机反应研究的最新进展,包括加氢反应、氧化反应、羰基化反应、碳碳键形成反应、酯化反应和酶催化反应的研究现状;同时,还介绍了超临界二氧化碳作为反应底物用于合成碳酸酯和氨基甲酸酯的研究进展;并对未来的发展进行了展望。
英文摘要：
The progress on organic reactions in this paper, which ineluds hydrogenation, oxidation, and enzymatic reaction. The synthesis of carbonates supercriticaI carbon dioxide in recent five years is reviewed in carbonylation, carbon-carbon bond formation, esterification and carbamates using supercritical carbon dioxide as substrate is also discussed. The outlook of the research area is provided.
同期刊论文项目
同项目期刊论文
An efficient and eco-friendly process for the conversion of carbon dioxide into oxazolones and oxazo
PdCl2-catalyzed heterocyclotrimerization in MeOH/scCO(2): A versatile approach to dimethyl pyridine-
Naturally occurring alpha-amino acid catalyzed coupling of carbon dioxide with epoxides to afford cy
Palladium-catalyzed homo-coupling of boronic acids with supported reagents in supercritical carbon d
PS-HQ: More convenient in situ polymeric cocatalyst for the PdCl2-catalyzed acetalization in supercr
Convenient one-pot synthesis of multisubstituted tetrahydropyrimidines via catalyst-free multicompon
Highly efficient three-component synthesis of polysubstituted 2,5-dihydro-1,3-oxazin-6-ones under mi
Hydroalkylation leading to heterocyclic compounds (Part 2): practical synthesis of polysubstituted 1
Hydroalkylation leading to heterocyclic compounds. Part 1: New strategies for the synthesis of polys
Palladium(II)-Catalyzed Highly Regio- and Stereoselective Synthesis of 2-
Chloro-1,3-diene Derivativ
Palladium-Catalyzed Direct Oxidation of Alkenes with Molecular
Oxygen: General and Practical Methods
Tris(4-anisyl)phosphine as an Efficient and Practical Reagent
for the Synthesis of (E)-2-Benzylidene
Palladium-Catalyzed Alkenylation of 1,2,3-Trizoles with Terminal Conjugated
Alkenes by Direct C–H Bo
Synthetic Approach to Polysubstituted Furans: An
Efficient Addition/Oxidative Cyclization of
Alkynoa
L-Proline-catalyzed five-component domino reaction leading to
multifunctionalized 1,2,3,4-tetrahydro
One-Pot Silver-Catalyzed and
PIDA-Mediated Sequential Reactions:
Synthesis of Polysubstituted Pyrrol
Bronsted acid-promoted domino reactions: a novel one-pot three-component synthesis of 3,4,5-trisubst
Iron-Catalyzed Domino Process for the Synthesis of
r-Carbonyl Furan Derivatives via One-Pot
Cyclizat
Naturally occurring a-amino acid: a simple and inexpensive catalyst for the selective synthesis of 5
Copper-catalyzed domino rearrangement/dehydrogenation oxidation/carbene oxidation for one-pot regios
Silver-Catalyzed Difunctionalization of
Terminal Alkynes: Highly Regio- and
Stereoselective Synthesi
DABCO-induced [2+2+2]-cycloaddition reaction of ethyl propiolate and aryl aldehydes for the synthesi
Copper-Catalyzed Intermolecular Oxidative [3 + 2] Cycloaddition between
Alkenes and Anhydrides: A Ne
Expedient Synthesis of Functionalized Conjugated Enynes:
Palladium-Catalyzed Bromoalkynylation of Al
Silver-Catalyzed One-Pot Cyclization Reaction of Electron-
Deficient Alkynes and 2-Yn-1-ols: An Effi
Facile Synthesis of Trisubstituted Allenynes by Phosphane-Mediated
Deoxygenation of 2,4-Pentadiyn-1-
Synthesis of tetrasubstituted furans via sequential Pd(OAc)2/Zn(OTf)2 catalyzed oxidation and cycliz
Nano-Cu2O-Catalyzed Formation of C C and C O Bonds:One-Pot Domino Process for Regioselective Synthes
Stereoselective synthesis of tetrsubstituted olefins via palladium-catalyzed three-component couplin
Practical synthesis and mechanistic study of polysubstituted tetrahydropyrimidines with use of domin
Pd-catalyzed and CsF-promoted reaction of bromoalkynes with isocyanides: regioselective synthesis of
Switch of Selectivity in the Synthesis of alpha-Methylene-gamma-Lactones: Palladium-Catalyzed Interm
Chlorine-free copper-catalyzed oxidative synthesis of 1,3,4-oxadiazoles with molecular oxygen as the
Acetoxypalladation of unactivated alkynes and capture with alkenes to give 1-acetoxy-1,3-dienes taki
A new three-dimensional metal-organic framework constructed from 9,10-anthracene dibenzoate and Cd(I
Palladium-Catalyzed Intermolecular Dehydrogenative Anninohalogenation of Alkenes under Molecular Oxy
Nano-Cu(2)O-Catalyzed Formation of C-C and C-O Bonds: One-Pot Domino Process for Regioselective Synt
Carbon Dioxide Triggered and Copper-Catalyzed Domino Reaction: Efficient Construction of Highly Subs
Palladium-Catalyzed Alkenylation of 1,2,3-Trizoles with Terminal Conjugated Alkenes by Direct C-H Bo
One-Pot Silver-Catalyzed and PIDA-Mediated Sequential Reactions: Synthesis of Polysubstituted Pyrrol
Expedient Synthesis of Functionalized Conjugated Enynes: Palladium-Catalyzed Bromoalkynylation of Al
Tris(4-anisyl)phosphine as an Efficient and Practical Reagent for the Synthesis of (E)-2-Benzylidene
Practical Synthesis of Polysubstituted Imidazoles via Iodine- Catalyzed Aerobic Oxidative Cyclizatio
Copper-catalyzed electrochemical synthesis of alkylidene lactones from carbon dioxide and 1,4-diaryl
Copper-Catalyzed Synthesis of Substituted Benzothiazoles via Condensation of 2-Aminobenzenethiols wi
Pd(II)-Catalyzed Sequential C-C/C-O Bond Formations: A New Strategy to Construct Trisubstituted Fura
Palladium-Catalyzed Bond Reorganization of 1,3-Diynes: An Entry to Diverse Functionalized 1,5-Dien-3
Synthesis of 2-Aminobenzoxazoles and 3-Aminobenzoxazines via Palladium-Catalyzed Aerobic Oxidation o
A New Series of C-6 Unsubstituted Tetrahydropyrimidines: Convenient One-Pot Chemoselective Synthesis
Ni(salphen)-based metal-organic framework for the synthesis of cyclic carbonates by cycloaddition of
Copper (I) catalyzed synthesis of 1,3-oxazolidin-2-ones from alkynes, amines, and carbon dioxide und
Palladium(II)-Catalyzed Highly Regio- and Stereoselective Synthesis of 2-Chloro-1,3-diene Derivative
Synthesis of 4H-cyclopenta[c]furans via cooperative PdCl2-FeCl2 catalyzed cascade cyclization reacti
A mixed-valence lanthanide metal-organic framework, templated by 2,2 '-bipyridine formed in situ rea
Palladium-Catalyzed Sequential Formation of C-C Bonds: Efficient Assembly of 2-Substituted and 2,3-D
Carbon-Carbon Bond Formation: Palladium-Catalyzed Oxidative Cross-Coupling of N-Tosylhydrazones with
Synthesis, Structures, and Properties of Two Three-Dimensional Metal-Organic Frameworks, Based on Co
Access to C(sp(3))-C(sp(2)) and C(sp(2))-C(sp(2)) Bond Formation via Sequential Intermolecular Carbo
Copper(I)-Catalyzed Synthesis of 2,5-Disubstituted Furans and Thiophenes from Haloalkynes or 1,3-Diy
Synthesis of delta-Bromo gamma,delta-Unsaturated Carbonyl Compounds via Palladium-Catalyzed Bromoalk
A novel asymmetric di-Ni(II) system as a highly efficient functional model for phosphodiesterase: sy
Pd-Catalyzed cyclization reaction: a convenient domino process for synthesis of alpha-carbonyl furan
Palladium-Catalyzed Bromoalkynylation of C-C Double Bonds: Ring-Structure-Dependent Synthesis of 7-A
Highly regio- and stereoselective synthesis of 1,3-enynes from unactivated ethylenes via palladium-c
Palladium-Catalyzed Carbonation-Diketonization of Terminal Aromatic Alkenes via Carbon-Nitrogen Bond
Effective synthesis of symmetrical oxygen- and nitrogen-heterocycles from electron-deficient alkynes
An aerobic [2+2+2] Cyclization via Chloropalladation: From 1,6-Diynes and Acrylates to Substituted A
Facile Synthesis of (E)-Alkenyl Aldehydes from Allyl Arenes or Alkenes via Pd(II)-Catalyzed Direct O
DABCO-Catalyzed Oxidation of Deoxybenzoins to Benzils with Air and One-Pot Synthesis of Quinoxalines
Palladium-Catalyzed Cross-Coupling Reactions of Electron-Deficient Alkenes with N-Tosylhydrazones: F
Hydrogenation of methyl laurate to produce lauryl alcohol over Cu/ZnO/Al2O3 with methanol as the sol
Synthesis of unsymmetrical organic carbonates catalyzed by zirconium phosphonate functionalized with
Elimination of the negative effect of nitrogen compounds by CO2–water in the hydrocracking of anthra
Regioselective Oxyalkylation of Vinylarenes Catalyzed by Diatomite-Supported Manganese Oxide Nanopar
Selective Iodine-Catalyzed Intermolecular Oxidative Amination of C(sp3)H Bonds with ortho-Carbonyl-S
A Highly anti-Selective Asymmetric Henry Reaction Catalyzed by Chiral Copper Complex and Application
Highly active and selective synthesis of imines from alcohols and amines or nitroarenes catalyzed by
Electrochemical tandem synthesis of oximes from alcohols using KNO3 as the nitrogen source, mediated
Synthesis, structures, and luminescent properties of four new 3D lanthanide metal-organic frameworks
Silver-Assisted Difunctionalization of Terminal Alkynes: Highly Regio- and Stereoselective Synthesis
Palladium-Catalyzed CC Coupling of Aryl Halides with Isocyanides: An Alternative Method for the Ster
Pd(II) immobilized on mesoporous silica by N-heterocyclic carbene ionic liquids and catalysis for hy
Synthesis of cyclic carbonates and dimethyl carbonate using CO2 as a building block catalyzed by MOF
Enantioselective and Regioselective Friedel–Crafts Alkylation of Pyrroles with Nitroalkenes Catalyze
Multi-functional Metal-organic frameworks based on H4mdip: crystal structure, photoluminescence, sel
Four new metal–organic frameworks constructed from H2DBTDC-O2 (H2DBTDC-O2 ? dibenzothiophene-5,50-di
Highly Enantioselective Henry Reaction in Water Catalyzed by a Copper-Tertiary Amine Complex and App
Highly efficient synthesis of 2,3,4-trisubstituted furans via silver-catalyzed sequential nucleophil
Copper-Catalyzed Aerobic C(sp(2))-H Functionalization for C-N Bond Formation: Synthesis of Pyrazoles
Facile synthesis of benzofurans via copper-catalyzed aerobic oxidative cyclization of phenols and al
Facile Synthesis of Trisubstituted Allenynes by Phosphane-Mediated Deoxygenation of 2,4-Pentadiyn-1-
Iron-Catalyzed Domino Process for the Synthesis of alpha-Carbonyl Furan Derivatives via One-Pot Cycl
Silver-Catalyzed Difunctionalization of Terminal Alkynes: Highly Regio- and Stereoselective Synthesi
Palladium-Catalyzed Direct Oxidation of Alkenes with Molecular Oxygen: General and Practical Methods
PdCl2(HNMe2)(2)-Catalyzed Highly Selective Cross [2+2+2] Cyclization of Alkynoates and Alkenes under
Synthetic Approach to Polysubstituted Furans: An Efficient Addition/Oxidative Cyclization of Alkynoa
Silver-Catalyzed One-Pot Cyclization Reaction of Electron-Deficient Alkynes and 2-Yn-1-ols: An Effic
An Efficient Synthesis of Polysubstituted Pyrroles via Copper-Catalyzed Coupling of Oxime Acetates w
Facile Synthesis of Dibranched Conjugated Dienes via Palladium-Catalyzed Oxidative Coupling of N-Tos
Palladium-Catalyzed Oxidative Coupling of Aromatic Primary Amines and Alkenes under Molecular Oxygen
Copper-Catalyzed Intermolecular Oxidative Cyclization of Haloalkynes: Synthesis of 2-Halo-substitute
Aerobic Oxidative Coupling between Carbon Nucleophiles and Allylic Alcohols: A Strategy to Construct
Facile one-pot synthesis of VxOy@C catalysts using sucrose for the direct hydroxylation of benzene t
Catalytic hydroxylation of benzene to phenol with hydrogen peroxide using catalysts based on molecul
Theoretical study on the reaction of CO2 and 2-aminobenzonitrile to form quinazoline-2,4(1H,3H)-dion
Cobalt-catalyzed oxidative [3 + 2] cycloaddition reactions: an efficient synthesis of pyrrolo- and i
Metal-free synthesis of polysubstituted oxazoles via a decarboxylative cyclization from primary &alp
A Highly Tunable Stereoselective Dimerization of Methyl Ketone: Efficient Synthesis of E- and Z-1,4-
Iron-Catalyzed Synthesis of 2-Vinylquinolines via sp3 CH Functionalization and Subsequent CN Cleavag
A Rapid and Efficient Access to Polysubstituted Imidazoles via Iodine-Catalyzed Tandem Oxidative Cyc
Natural alpha-amino acids applied in the synthesis of imidazoles[1,5-a]N-heterocycles under mild con
Palladium-assisted multicomponent cyclization of aromatic aldehydes, arylamines and terminal olefins
Immobilized 1,1,3,3-Tetramethylguanidine Ionic Liquids as the Catalyst for Synthesizing Propylene Gl
Efficient synthesis of quinazoline-2,4(1H,3H)-diones from CO2 and 2-aminobenzonitriles in water with
Synthesis of Chromones through LiOtBu/Air-Mediated Oxidation and Regioselective Cyclization of o-Hyd
Copper-Catalyzed Formal C-N Bond Cleavage of Aromatic Methylamines: Assembly of Pyridine Derivatives
Direct Arylation of Imidazo[1,2-a]pyridine at C-3 with Aryl Iodides, Bromides, and Triflates via Cop
Metal-Free Synthesis of 2-Aminobenzothiazoles via Aerobic Oxidative Cyclization/Dehydrogenation of C
Highly selective synthesis of phenol from benzene over a vanadium-doped graphitic carbon nitride cat
Transition-Metal-Catalyzed Domino Reactions: Efficient One-Pot Regiospecific Synthesis of Highly Fun
Palladium-catalyzed tandem reaction of o-aminophenols, bromoalkynes and isocyanides to give 4-amine-
A chiral mixed metal-organic framework based on a Ni(saldpen) metalloligand: synthesis, characteriza
Pd(II)-Catalyzed Highly Regio- and Stereoselective Assembly of C-C Double Bonds: An Efficient Method
期刊信息
位置：