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中文摘要：
电致化学发光（ECL）一般是在电极表面或附近发生的，通常人们可以通过调节电极的相对位置，改变对电极所施加的电位及改变电极材料来改变ECL的强度及特性，以获得最好的检测结果。目前所有有关ECL的研究都是在室温下进行，但事实上发生在电极表面的ECL不但与发光物质在电极表面的扩散有关，与发光物质的传质速率等动力学因素也密切相关，而电极表面的温度对这些因素有着重要影响。因此研究电极表面温度对ECL反应的影响，对于进一步提高ECL分析方法的灵敏度、选择性、稳定性有重要意义。本课题拟研制一种结构和性能良好的，可用于进行ECL研究的热控微电极系统，并对热控ECL的理论问题开展深入研究，在此基础上开展各种电极材料（包括修饰电极）上的热控ECL的研究，以期在应用方面，特别是在生物活性物质的ECL检测方面有较大突破，最终还要将该系统与毛细管电泳技术结合，建立一个性能良好的毛细管电泳- - 热控ECL检测系统。
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期刊论文
Study on the kinetics of keto-enol tautomerism of p-hydroxyphenylpyruvic acid using capillary electr
Design and fabrication of micro-electrochemical cell for the study of ionic liquid-mediated electroc
A new electrochemilumine- scent detection system equipped with an electrically heating controlled mi
Separation and determination of peptide hormones by CE-LIF coupling with transient pseudo-isotachoph
Identification ofβ-Sitosterol, stigmasterol and ergosterin in A. roxburghii. using supercritical flu
A novel electrochemiluminescent sensor for methamphetamine hydrochloride based on multiwall carbon n
Electrochemiluminescent behavior of lucigenin at an electrically heating controlled cylindrical micr
Study on the photocatalytic degradation of methyl orange in water using Ag/ZnO as catalyst by liquid
Inhibited Ru(bpy)32+ electrochemiluminescence related to electrochemical oxidation activity of inhib
Using of multiple PCR and capillary electrophoresis with chemiluminescent detection for simultaneous
A new capillary electrophoresis( electrochemiluminescent detection system equipped with an electrica
Preparation and application of L-cysteine- modified CdSe/CdS core/shell nanocrystals as a novel fluo
The electrochemiluminescent behavior of luminol on an electrically heating controlled microelectrode
A New Method for Determination of the Peptide Hormone of Brain and Intestine by Capillary Electropho
A flow-injection analysis system equipped with a newly designed electrochemiluminescent detector and
A new electrochemilu- minescent sensing system for glucose based on the electrochemiluminescent reac
An organically modified sol-gel membrane for detection of lead ion by using 2-Hydroxy-1- naphthaldeh
An electrochemiluminescent biosensor for vitamin C based on inhibition of luminol electrochemilumine
Electrochemiluminescent behaviors of luminol on the glassy carbon electrode modified by Coblat(II) p
Determination of carbamates in nature water based on the enhancement of electrochemilu- minescent of
An Electrochemi- luminescent detector based on multi-wall- carbon-nanotube/Nafion/Ru(bpy)32+ composi
Structure and properties of SnS films prepared by electro- deposition from aqueous solution containi
A new electrochemiluminescent detection system equipped with an electrically heated carbon paste ele
Investigation on the electrochemiluminescent behaviors of oxypurinol in alkaline Ru(bpy)32+ solution
Capillary electrophoresis chemiluminescent detection system equipped with a two-step postcolumn flow
Enhancement of eletrochemilumine- sence of lucigenin by ascorbic acid at single-wall carbon nanotube
Hybridization biosensor using 2-nitroacridone as electrochemical indicator for detection of short DN
Electrochemical Biosensors Based on Hairpin DNA Probe using 2-nitroacridone as electrochemical indic
Simultaneous separation of basic and acidic proteins using 1-butyl-3-methylimidazolium-based ion liq
Synthesis of a new fluorescent probe 7-oxobenzo[b][1,10] phenanthroline-12(7H)- sulfonic acid and in
Separation and detection of isoquinoline alkaloids using microemulsion electrokinetic chromatography
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