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化学反应工程
  • 项目名称：化学反应工程
  • 项目类别：国家杰出青年科学基金
  • 批准号：20425619
  • 申请代码：B0604
  • 项目来源：国家自然科学基金
  • 研究期限：2005-01-01-2008-12-31
  • 项目负责人：李永丹
  • 负责人职称：教授
  • 依托单位：天津大学
  • 批准年度：2004
中文摘要：

对极其重要的工业催化剂水煤气变换、加氢精制催化剂的制备与使用性能优化有系统研究，特别是对这些催化剂和颗粒填充床的机械强度建立了基础理论框架。对催化剂使用中机械强度的丧失机理、填充床的冷热态机械强度模型、催化剂颗粒机械性能评价和优化理论有系统建树。对甲烷催化裂解制无CO的氢气适应燃料电池需要有领先的研究，论文被Energy & Fuels选为体现该杂志质量和影响的代表作，对此反应中纳米碳材料结构选择性有很大进展，最

中文主题词： 催化剂制备;颗粒机械强度
成果综合统计
成果类型
数量
  • 期刊论文
  • 会议论文
  • 专利
  • 获奖
  • 著作
  • 165
  • 35
  • 0
  • 0
  • 0
期刊论文
L-苯丙氨酸在单壁碳纳米管上的吸附行为
处理方法对活性炭在流化床反应器内甲烷催化裂解制氢活性的影响
金属膜开发应用研究新进展
Co/HZSM-5分子筛催化醛氨缩合反应活性的研究
Pd-Cu合金复合膜的制备及表征
处理方法对碳纳米管织构性质及负载Pd-Pt催化剂萘加氢反应活性的影响
化学气相沉积法制备碳纳米管过程中NH3对其微观结构和石墨化程度的影响
提高FCC汽油辛烷值的技术进展
吸附法脱除催化裂化汽油中含硫化合物的研究
Analysis of oxygen permeation through dense ceramic membranes with chemical reactions of finite rate
Evidence of composition deviation of metal particles of a Ni–Cu/Al2O3 catalyst during methane decomp
Effect of Metal-Support Interface on Hydrogen Permeation through Palladium Membranes
A high performance composite ionic conducting electrolyte for intermediate temperature fuel cell and
Modeling and simulation of a single direct carbon fuel cell
MCM-41 Overgrown on Y Composite Zeolite as Support of Pd-Pt Catalyst for Hydrogenation of Polyaromat
Tailoring the pore size of zeolite Y as the support of diesel aromatic saturation catalyst
Characterization of zirconia modified porous stainless steel supports for Pd membranes
介孔载体离子交换方式对其负载Pd-Pt催化剂加氢性能的影响
流化床与固定床中甲烷裂解制氢过程的比较
直接碳燃料电池研究进展
Methods for estimating Weibull parameters for brittle materials,
Adsorption of L-phenylalanine on single-walled carbon nanotubes
Preparation of Thin Palladium Composite Membranes and Application to Hydrogen/Nitrogen Separation
Vertically aligned carbon nanotube membranes on macroporous alumina supports
Mechanical Strength of Solid Catalysts: Recent Developments and Future Prospects
流化床中甲烷裂解制氢与催化剂再生过程研究
La、Ba离子对高温燃烧催化剂六铝酸盐结构和性质的影响
无模板剂二次生长法合成MFI分子筛膜的生长机理
制备条件对吸附剂脱硫性能的影响
高压乙醇中的无限稀释扩散系数:实验测定与模型评价
甲烷重整制氢气的研究进展
Suzuki Coupling Reactions in Ether-Functionalized Ionic Liquids: The Importance of Weakly Interactin
Biphasic Hydrogenation over PVP Stabilized Rh Nanoparticles in Hydroxyl Functionalized Ionic Liquids
Simulation of methane conversion to syngas in a membrane reactor: Part II: Model predictions
Treatment of the carbon nanofiber surfaces in mixed concentrated HNO3-H2SO4, and the catalytic activ
Synthesis of vertically aligned carbon nanotubes on macroporous alumina substrates
Study on non-hydrothermal synthesis and intercalation assembly of Zn-saponite
Synthesis and characterization of NiAl-HTLcs/saponite layer composites
Distribution of the Mechanical Strength of Solid Catalysts
Enhanced Activation and Decomposition of CH4 by the Addition of C2H4 or C2H2 for Hydrogen and Carbon
Preparation and characterization of Beta/MCM-41composite zeolite with a stepwise-distributed pore st
Effect of the sulfidation process on the mechanical properties of a CoMoP/Al2O3 hydrotreating cataly
Palladium nanoparticles stabilized by an ionic polymer and ionic liquid: a versatile system for C-C
High-Temperature Stability of Palladium Membranes on Porous Metal Supports with Different Intermedia
Effect of Alkaline Treatment on the Catalytic Performance of ZSM-5 Catalyst in Pyridine and Picoline
Thermodynamic Analysis of Hydrogen Production from Oxidative Steam Reforming of Ethanol
Effects of surface oxidation of carbon nanofibers in mixed concentrated HNO3-H2SO4 acid solution on
Low-temperature synthesis of carbon onions by chemical vapor deposition using a nickel catalyst supp
Electroless plating synthesis, characterization and permeation properties of Pd-Cu membranes support
Bamboo-shaped carbon nanotubes produced by catalytic decomposition of methane over nickel nanopartic
Effect of surface acid amount of Y zeolite on activity and sulfur tolerance of supported Pd-Pt catal
Study on sulfur tolerance of Pd-Pt catalyst supported on carbon nanofibers for hydrogenation of naph
Size effect on strength of alumina agglomerates
Influence of pretreatment condition of metal support on performance of metal supported hexaaluminate
Characterization and adsorption properties of porous carbon nanofiber granules
Promoting effects of doping ZnO into coprecipitated Ni-Al2O3 catalyst on methane decomposition to hy
Steam reforming of ethanol over Co3O4/CeO2 catalysts prepared by different methods
Physical activation and characterization of multi-walled carbon nanotubes catalytically synthesis fr
Unbiased estimation of Weibull parameters with the linear regression method
Fabrication and growth mechanism of carbon nanotubes by catalytic chemical vapor deposition
Statistical analysis of pellet size variation in commercial catalysts
Study on purification and tip-opening of CNTs fabricated by CVD
碱渣的综合治理与利用
Synthesis of pyridine and picolines over Co-modified HZSM-5 catalyst
Advances in catalytic hydrodenitrogenation
涂层浸渍法在Al_2O_3片上大面积合成碳纳米纤维,
MCM-41在微孔分子筛Y上的附晶生长
加氢脱氮催化研究的新进展
催化燃烧用金属整体催化反应器的制备及性能
结构化反应器的研究现状与发展前景
离子交换程序对Pd/Y催化剂萘加氢活性和耐硫性能的影响
柴油车排放的碳颗粒物微结构和化学分析
软模板法合成多级孔沸石分子筛及其催化性能研究进展
锌皂石的非水热合成与插层组装性能研究
CaxLa1-xMnAl11O19六铝酸盐催化剂上甲烷的催化燃烧
会议论文
微孔介孔分子筛在催化加氢中的应用,
Thermal stability of the alloy substrate combustion catalyst,
Preparation of a metal supported hexaaluminate catalyst for methane combustion, Stud. Surf. Sci. Cat
Modified HZSM-5 zeolite catalysts for synthesis of pyridine and picolins,
Effect of sequential desilication and dealumination on catalytic performance of ZSM-5 in Pyridine an
The doping effect of Mo on Fe/Al2O3 catalyst for methane decomposition reaction,
A model for simulating the direct carbon fuel cell,
Zirconia modified porous stainless steel used as support of Pd-membrane,
Design and tailoring the pore structure of zeolite Y for polyaromatics hydrogenation,
基于甲烷催化裂解反应的高效能量转化系统,
多级孔道的柴油芳烃加氢饱和催化剂载体的研究，
氢气还原对Co/Cu/Al_2O_3甲烷裂解催化剂的影响,
原位XRD跟踪甲烷裂解反应过程研究
氧化物层从合金基体脱落模型，
中温固体氧化物燃料电池铈基-碳酸盐复合电解质，
Hopcalite catalyst for ethylene oxidation at low temperature,
Experimental study on electrodialysis separation of nitric acid from glyoxal produced by acetaldehyd
A highly efficient power generation process from natural gas: An exergy analysis,
原位XRD对Fe催化剂上甲烷裂解反应的研究
甲烷裂解制清洁氢气中活性碳催化性能的研究,
Beta次级结构单元改性MCM-41的合成和芳烃加氢活性
Manufacture of carbon nanotube reinforced aluminum composite by in-situ catalytic synthesis,
China-German Symposium on “Particle and its interaction with particles”, October 24-31, Beijing
Effect of substitution to mirror plane cations of hexaaluminate for the activity of methane combusti
Efficiency of Energy Conversion: A revolution is expected, International Forum on Green Chemical Sci
Effect of sulfur compound on the activity of Pd-Pt/HY catalyst for aromatic hydrogenation,
Preparation of Thin Palladium Composite Membranes and Their Applications to Hydrogen Separation,
Investigation on pore structure of the supports of diesel aromatics saturation catalysts,
Syngas and hydrogen production from bio and fossil fuels,
Effect of sequential desilication and hydrothermal dealumination on the catalytic performance of ZSM
Composite zeolite used as the support of diesel aromatic saturation catalyst,
The activity and thiotolerance of a Pd-Pt catalyst supported on yttrium modified USY for tetralin hy
Production of COx-free hydrogen without CO2 emission via direct catalytic decomposition of methane,
化学能高效利用与能源转换效率,
催化裂化汽油脱硫吸附剂的制备及表征,
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