中文摘要：

采用软化学合成法合成出基面间距为0．70nm的层状二氧化锰（bir-MnO2），并利用表面吸附技术制备了层状二氧化锰／苯胺-邻甲氧基苯胺共聚物复合材料（bir—MnO2／P（An-co—oAs）），借助FTIR、XRD、SEM、TGA、四探针和充放电循环实验等测试手段对样品的结构与性能进行表征。结果表明，P（An-co-oAs）的引入，对复合材料中bir-MnO2的层状结构破坏较小，P（An-co-oAs）通过氢键和静电作用吸附在bir-MnO2的表面。与bir-MnO2相比，复合材料的电导率提高2个数量级。首次放电比容量由bir—MnO2的188mAh／g提高到复合材料的202mAh／g。

英文摘要：

Layered manganese oxide （bir-MnO2） with a basal spacing of 0.7nm was synthesized by soft chemistry synthesis method. The layered manganese oxide/poly（aniline-co-o-anisidine） composites were prepared by surface adsorption technique, and were characterized by FTIR, XRD, SEM, TGA, four-probe instrument and electrochemical measurement. The results show that the intercalation of P（An-co-oAs） has less effect on the layered structure of bir-MnO2. P（An-co-oAs） is adsorbed on surface of bir-MnO2 via the hydrogen bond and electrostatic action. The electrical conductivity of composites is by 2 orders of magnitude higher than that of birMnO2. The first discharge capacity is improved from 188mAh/g of bir-MnO2 to 202mAh/g of composite.