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中文摘要：
以纳米碳酸钙为模板，通过无皂乳液包覆法制备出以纳米碳酸钙为核聚合物为壳的复合颗粒，再通过酸溶合成聚合物空心球，分析制备过程的机理特别是对pH值的影响，
英文摘要：
In this paper, the composite particles consisting of cores of nano calcium carbonate and shells of polymer were prepared by soapless emulsion polymerization technology with nano calcium carbonate particles as templates. After dissolution with acid, the polymer hollow sphere was obtained. The preparation mechanism, especially the effects of pH, was analyzed.
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