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灌河口潮滩重金属累积特征及污染评价
  • ISSN号:0379-1726
  • 期刊名称:《地球化学》
  • 时间:0
  • 分类:P595[天文地球—地球化学;天文地球—地质学] X142[环境科学与工程—环境科学]
  • 作者机构:[1]南京信息工程大学大气科学学院海洋科学系,江苏南京210044, [2]南京大学海岸与海岛开发教育部重点实验室,江苏南京210093
  • 相关基金:国家自然科学基金(40371048)
中文摘要:

河口地区潮滩是重金属重要的“汇”。测定了灌河口(燕尾港)潮滩高中低滩的33个表面样粒度、重金属数据,研究了4根柱状样的重金属和粒度特征,利用地累积指数法、潜在生态危害指数法及富集指数法等评价指标,对灌河口重金属的污染状况进行了评价,并对其结果进行了相互比较和印证。分析结果显示,灌河口潮滩重金属的分布主要受水动力影响,特别是受粘土分布的控制。Cd与粒径Φ值相关性不显著,相关系数只有0.099,而与粘土含量呈明显正相关关系,Hg的变化趋势恰恰相反,其含量随着距离河口距离的加大反而有增加的趋势;其他元素的变化趋势不明显。重金属元素Zn、Pb、Cu、Hg含量变化走势基本相同,用Ⅱ作归一化标准元素归一化后,所有重金属元素的归一化值变化波动范围均比重金属含量值明显收窄,波峰和波谷有后延的趋势。灌河口滩涂总体重金属环境尚可,但存在一定程度的Hg、Cu污染富集。柱状样Hg、Cu的地累积污染指数总体上均呈现随深度增加而降低的趋势。

英文摘要:

The tidal flat in estuaries is an important "sink" of heavy metals. The grain sizes and heavy metal contents of 33 surface samples from the inner, middle and outer flats and of 4 core samples in Guanhe Estuary (Yanweigang) are determined. Index of geoaccumulation Igeo, potential ecological risk index R/and sediment enrichment factor KSEF are used to evaluate enrichment and pollution of heavy metals in Guanhe Estuary, and the evaluation results were compared and confirmed. The analytical results show that the distribution of heavy metals in Guanhe Estuary is mainly controlled by the estuarine tidal hydrodynamic system and particularly by the distribution of clay. Cd content has a weak correlation with the Φ value of grain size with a correlation coefficient of only 0. 99, but correlated closely with the clay content. Hg has a contrary distribution trend: its content increases with increasing distances from the estuary. Changes of contents of other elements are not so obvious with increasing distances from the estuary. The vertical distributions of Zn, Pb, Cu and Hg are almost the same on the whole. The vertical Li-normalized patterns of all the heavy metals have much narrower variation ranges than those of the original ones, and have a trend of deferred peaks and valleys with unchanged basic fluctuation trends. The environment in Guanhe Estuary is fairly good, only Hg and Cu reach a certain degree of pollution levels. The Igeo of Hg and Cu of a core sample shows overall decreasing trend with depth, showing an increasing trend of Hg and Cu pollution year after year. s:

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期刊信息
  • 《地球化学》
  • 中国科技核心期刊
  • 主管单位:中国科学院
  • 主办单位:中国科学院广州地球化学研究所 中国矿物岩石地球化学学会
  • 主编:傅家谟
  • 地址:广州市五山1131信箱
  • 邮编:510640
  • 邮箱:DQHX@GIG.AC.CN
  • 电话:020-85290046
  • 国际标准刊号:ISSN:0379-1726
  • 国内统一刊号:ISSN:44-1398/P
  • 邮发代号:2-813
  • 获奖情况:
  • 中国自然科学核心期刊,2000年中国科学院优秀期刊一等奖,百种中国杰出学术期刊,中国科协优秀期刊,中国期刊方阵“双效”期刊
  • 国内外数据库收录:
  • 美国化学文摘(网络版),日本日本科学技术振兴机构数据库,中国中国科技核心期刊,中国北大核心期刊(2004版),中国北大核心期刊(2008版),中国北大核心期刊(2014版),英国英国皇家化学学会文摘,中国北大核心期刊(2000版)
  • 被引量:18850